N-[(E)-4-(Methylsulfonyl)benzylidene]-3-nitroaniline
نویسندگان
چکیده
In the title compound, C(14)H(12)N(2)O(4)S, the dihedral angle between the two aromatic rings is 35.65 (12)°. The crystal packing is stabilized by weak C-H⋯O hydrogen bonds and aromatic π-π ring stacking inter-actions [minimum ring centroid separation = 3.697 (3) Å].
منابع مشابه
(E)-2-Methyl-N-[4-(methylsulfonyl)benzylidene]aniline
Mol-ecules of the title compound, C(15)H(15)NO(2)S, display an E configuration with respect to the C=N double bond. The crystal structure is stabilized by weak C-H⋯O hydrogen bonds. The dihedral angle between the two aromatic ring planes is 50.41 (12)°.
متن کامل(E)-N-[4-(Methylsulfonyl)benzylidene]aniline
The mol-ecule of the title compound, C(14)H(13)NO(2)S, displays a trans configuration with respect to the C=N double bond. The dihedral angle between the two aromatic ring planes is 62.07 (18)°.
متن کامل(E,E)-N,N′-Bis[4-(methylsulfonyl)benzylidene]ethane-1,2-diamine
In the crystal structure of the title Schiff base compound, C(18)H(20)N(2)O(4)S(2), the mol-ecule lies across a crystallographic inversion centre. The torsion angle of the N-C-C-N fragment is 180°, as the inversion centre bis-ects the central C-C bond. The crystal packing is stabilized by C-H⋯O hydrogen bonds and aromatic π-π stacking inter-actions with a centroid-centroid distance of 3.913 (2) Å.
متن کامل(E)-4-Chloro-N-[4-(methylsulfonyl)benzylidene]aniline
In the crystal structure of the title compound, C(14)H(12)ClNO(2)S, the mol-ecules display a trans conformation with respect to the C=N double bond. The dihedral angle between the methyl-sulfonyl benzene and chloro-benzene rings is 59.59 (8)°. The crystal packing is stabilized by weak C-H⋯O inter-actions and by π-π stacking inter-actions between inversion-related methyl-sulfonyl benzene rings [...
متن کاملN-(4-Methylbenzyl)-3-nitroaniline
In the title compound, C(14)H(14)N(2)O(2), the angle between the mean plane of the N-methyl-3-nitro-aniline system (r.m.s. deviation = 0.0185 Å) and the p-tolyl unit is 89.79 (4)°. In the crystal, hydrogen-bonded chains running along [10-1] are generated by the linking of neighbouring mol-ecules via N-H⋯O and C-H⋯O hydrogen bonds involving the 3-nitro-aniline systems and forming R(2) (2)(8) mot...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011