Molecular interaction studies in binary mixtures containing aniline, toluene and n-butanol
نویسندگان
چکیده
Ultrasonic velocity and density values have been measured at 303 K in binary mixtures containing aniline, toluene and n-butanol; and the thermodynamical approach is applied to evaluate the mixtures’ molar volume, adiabatic compressibility, intermolecular free length and excess values. The observed results are interpreted in terms of molecular interaction between the components of the mixtures. Observed excess values and their fittings of R-K type equations lend further support to the observation made in the binary system.
منابع مشابه
Volumetric properties of {n-butyl acetate + 1-butanol + 1,2- butanediol} at temperature between [298.15 ,303.15 and 308.15] K.
Densities and excess molar volume of the binary and ternary mixtures formed by nbutylacetate+ 1-butanol + 1,2-butanediol were measured at (298.15, 303.15, and 308.15) K forthe liquid region and at ambient pressure (81.5) k Pa , for the whole composition range. Theexcess molar volumes,VmE and excess partial molar volume ViE ,were calculated fromexperimental densities.The excess molar volumes are...
متن کاملStudy of Volumetric Properties of N,N-Dimethyl Acetamide and 1-Alkanols Binary Mixtures at 298.15 K
In this study, the densities, excess molar volumes and partial molar volumes of four binary systems containing N,N-dimethyl acetamide (DMAc) with 1-alkanols (1-butanol up to 1-heptanol) are measured at 298.15 K. The results showed both constructive and expansive excess volumetric behavior for studying binary mixtures. Deviation values of heavy alcohol have more positive and less negative excess...
متن کاملMeasurement of Selected Thermophysical and Viscosity of Binary Mixtures of Nitromethane with 2-Propanol, 2-Butanol and 2-Pentanol
The density and viscosity values at T= (293.15 to 323.15) K for binary mixtures of nitromethane with 2-propanol, 2-butanol and 2-pentanol were measured over the entire composition range. From the experimental data, excess molar volumes, thermal expansion coefficients, excess thermal expansions, partial molar volumes at infinite dilution and deviations in viscosity were calculated. The results w...
متن کاملPrediction and Comparison of the Effect of N-butanol and Ethanol Addition to the Biodiesel-diesel Fuel Mixture on the Performance and Emissions Characteristics of a Diesel Engine
The main objective of this research is to study the effects of n-butanol and ethanol addition to the biodiesel-diesel fuel mixture on the performance and emission characteristics of a CI engine. The experimental tests were performed on a diesel engine. The RSM (Response Surface Methodology) method was used to develop mathematical models based on experimental data. According to the results, the ...
متن کاملImportance of Molecular Structure on the Thermophoresis of Binary Mixtures.
Using thermal lens spectroscopy, we study the role of molecular structural isomers of butanol on the thermophoresis (or Soret effect) of binary mixtures of methanol in butanol. In this study, we show that the thermal lens signal due to the Soret effect changes its sign for all the different concentrations of binary mixtures of butanol with methanol except for the one containing tertiary-butanol...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2011