Nitrogen diffusion mechanism in the R2Fe17 lattice

نویسندگان

  • Y. D. Zhang
  • D. P. Yang
چکیده

In this report, a diffusion analysis has been extended to a lattice containing two interstitial sites, and the results obtained are used to understand: ~1! the formation of a nitrided/unnitrided N configuration for intermediate N content and ~2! the abnormally small ~apparent! diffusion frequency factor, both of which characterize the newly developed R2Fe17 nitrides. It turns out that the diffusion mechanism for N atoms in the R2Fe17 lattice is a chemical reaction diffusion rather than a free-diffusion process. © 1995 American Institute of Physics.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Diffusion of nitrogen in R2Fe17 (R =rare earth) compounds determined by the Kissinger method

The activation energy of nitrogen diffusion in R2Fe,, (R=rare earth) compounds has been determined by applying the Kissinger method to analyse the differential scanning calorimetry (DSC) traces of nitrogenated R2Fe1, compounds. The nitrogen outgas that starts when the nitrides are heated above about 300 “C is a typical decomposition reaction of the type solid + solid + gas to which the Kissinge...

متن کامل

DIFFUSION LAYER GROWTH MECHANISM IN ASPN METHOD USING AN IRON CAGE FOR ST52 STEEL

- The mechanism of diffusion layer growth in plasma nitrided coatings applied on a St52 steel using an active screen is investigated. The nitriding was performed at 450,500 and 550 ◦C temperature nitriding times of 5, 10 and 15 h, in a gas mixture containing 20 vol. % H2: 80 vol. % N2 and DC-pulsed plasma nitriding unit. The surface, cross section and the thickness of diffusion of specimens ...

متن کامل

بررسی سینتیکی و تعیین مکانیزم واکنش پودر هیدراید تیتانیم با مذاب آلومینیم خالص

In this research, the reaction kinetics of TiH2 powder in contact with pure aluminum melt at various temperatures on the basis of measuring the released hydrogen gas pressure was studied. To determine the mechanism the reaction, after Solidification of samples, interface of TiH2 powder in contact with melt was studied. The results showed that PH2-time curves had three regions. In the first and...

متن کامل

Introduced a Modified Set of Boundary Condition of Lattice Boltzmann Method Based on Bennett extension in Presence of Buoyancy Term Considering Variable Diffusion Coefficients

Various numerical boundary condition methods have been proposed to simulate various aspects of the no-slip wall condition using the Lattice Boltzmann Method. In this paper, a new boundary condition scheme is developed to model the no-slip wall condition in the presence of the body force term near the wall which is based on the Bennett extension. The error related to the new model is smaller tha...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 1996