Chiral cobalt-catalyzed enantioselective aerobic oxidation of α-hydroxy esters.
نویسندگان
چکیده
A chiral cobalt-catalyzed enantioselective aerobic oxidative kinetic resolution of (±)-α-hydroxy esters, using molecular oxygen as a sole oxidant, is reported and a maximum of selectivity factor (s) 31.9 was achieved with >99% enantiomeric excess for unreacted α-hydroxy esters.
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عنوان ژورنال:
- Chemical communications
دوره 46 38 شماره
صفحات -
تاریخ انتشار 2010