4-(4-Chlorophenyl)-N-[(E)-4-(dimethylamino)benzylidene]-1,3-thiazol-2-amine
نویسندگان
چکیده
The title compound, C(18)H(16)ClN(3)S, adopts an extended mol-ecular structure. The thia-zole ring is inclined by 9.2 (1) and 15.3 (1)° with respect to the chloro-phenyl and 4-(dimethyl-amino)-phenyl rings, respectively, while the benzene ring planes make an angle of 19.0 (1)°. A weak inter-molecular C-H⋯π contact is observed in the crystal structure.
منابع مشابه
2-Chloro-N′-[4-(dimethylamino)benzylidene]-N-[4-(3-methyl-3-phenylcyclobutyl)-1,3-thiazol-2-yl]acetohydrazide
The mol-ecular conformation of the title compound, C(25)H(27)ClN(4)OS, is stabilized by an intra-molecular benzyl-idine C-H⋯N(thia-zole) hydrogen bond. The thiazole ring makes dihedral angles of 12.0 (3) and 20.4 (2)°, respectively, with the phenyl and benzene rings, while the phenyl and benzene rings make a dihedral angle of 22.6 (2)°. The crystal packing involves weak inter-molecular thia-zol...
متن کامل(1R*,2R*)-1-(4-Chlorophenyl)-4-dimethylamino-1-(3-methoxy-2-naphthyl)-2-(1-naphthyl)butan-2-ol
In the title compound, C(33)H(32)ClNO(2), the benzene ring is oriented at dihedral angles of 6.23 (5) and 66.44 (5)° with respect to the two naphthalene ring systems. An intra-molecular O-H⋯N hydrogen bond between the hydr-oxy H atom and the amine N atom generates an S(6) ring.
متن کامل2-[6-(4-Chlorophenyl)imidazo[2,1-b][1,3]thiazol-2-yl]-N′-[(E)-4-methoxybenzylidene]acetohydrazide
In the imidazo[2,1-b][1,3]thia-zole group of the title compound, C(21)H(17)ClN(4)O(2)S, the dihedral angle between the thia-zole and imidazole rings is 1.9 (2)°. The mean plane of this group makes dihedral angles of 5.5 (2) and 39.9 (2)° with the benzene rings of the chloro-phenyl and meth-oxy-phenyl groups, respectively. The dihedral angle between these two benzene rings is 34.4 (2)°. In the c...
متن کاملN-[4-(Dimethylamino)benzylidene]-4H-1,2,4-triazol-4-amine
The title compound, C(11)H(13)N(5), is a Schiff base synthesized by the reaction of 4-amino-4H-1,2,4-triazole and 4-(dimethyl-amino)-benzaldehyde. The dihedral angle between the benzene and triazole rings is 43.09 (11)°. The crystal structure displays weak C-H⋯N inter-actions.
متن کامل(Z)-2-Amino-5-[2,4-dimethoxy-6-(4-methoxystyryl)benzylidene]-1,3-thiazol-4(5H)-one methanol solvate
In the crystal structure of the title compound, C(21)H(20)N(2)O(4)S·CH(3)OH, mol-ecules are linked into chains by a series of inter-molecular N-H⋯O, N-H⋯N and O-H⋯O hydrogen bonds. The mol-ecular structure shows a double bond with Z geometry, connecting the thia-zolone and resveratrol units. The dihedral angle between the thiazolone ring and the nearest dimethoxy-benzene ring is 53.02 (7)°.
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011