2-[(4-Chlorophenyl)iminomethyl]hydroquinone
نویسندگان
چکیده
The title compound, C(13)H(10)ClNO(2), exists in the phenol-imine form in the crystal, and the aromatic rings are oriented at a dihedral angle of 2.82 (9)°. An intra-molecular O-H⋯N hydrogen bond results in the formation of a planar six-membered ring. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into chains.
منابع مشابه
(E)-2-[(4-Chlorophenyl)iminomethyl]-4-(trifluoromethoxy)phenol
The title compound, C(14)H(9)ClF(3)NO(2), crystallizes in a phenol-imine tautomeric form, with a strong intra-molecular O-H⋯N hydrogen bond. The dihedral angle between the two benzene rings is 47.62 (9)°. In the crystal, mol-ecules are linked into chains along the c axis by C-H⋯O hydrogen bonds, and weak C-H⋯π inter-actions involving both benzene rings are also observed.
متن کامل4-Bromo-2-[(E)-(4-chlorophenyl)iminomethyl]phenol
In the title compound, C(13)H(9)BrClNO, the dihedral angle between the substituted benzene rings is 43.90 (11)°. Strong intra-molecular O-H⋯N hydrogen bonds generate S(6) ring motifs. The crystal structure features short intemolecular Br⋯Br [3.554 (2) Å] and Cl⋯Cl [3.412 (2) Å] contacts. The crystal packing is further stabilized by inter-molecular C-H⋯O and C-H⋯π inter-actions.
متن کامل(E)-2-[(2-Chlorophenyl)iminomethyl]-4-methylphenol
The mol-ecule of the title compound, C(14)H(12)ClNO, adopts the enol-imine tautomeric form, with an intra-molecular O-H⋯N hydrogen bond. In the mol-ecule, the two benzene rings are twisted with respect to each other by 30.6 (2)°. The crystal structure is stabilized by inter-molecular C-H⋯π inter-actions.
متن کامل(2-{[2-Carboxylato-1-(4-chlorophenyl)ethyl]iminomethyl}phenolato-κ3 O,N,O′)(1H-imidazole-κN 3)copper(II) monohydrate
The Cu(II) atom of the title complex, [Cu(C(16)H(12)ClNO(3))(C(3)H(4)N(2))]·H(2)O, has a distorted square-planar coordination geometry formed by a tridentate Schiff base dianion and an imidazole ligand. The imidazole is nearly coplanar with the coordination plane, the dihedral angle between the planes being 3.73 (12)°. In the Schiff base ligand, the two benzene rings are oriented at a dihedral ...
متن کامل4-Chloro-2-[(E)-(2-chlorophenyl)iminomethyl]phenol
The title compound, C(13)H(9)Cl(2)NO, was crystallized from a methanol solution of 5-chloro-salicylaldehyde and o-chloro-aniline. The mol-ecule displays a trans configuration with respect to the imine C=N double bond. The N atom is involved in an intra-molecular O-H⋯N hydrogen bond. The two aromatic rings are essentially coplanar, the dihedral angle between them being 7.1 (1)°. A C-H⋯π inter-ac...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009