(Z)-9-(1,2-Dichlorovinyl)-9H-carbazole
نویسندگان
چکیده
There are two independent mol-ecules in the asymmetric unit of the title compound, C14H9Cl2N, in which the dihedral angles between the dichloro-vinyl unit (r.m.s. deviations = 0.0003 and 0.0009 Å), and the carbazole ring are 87.77 (3) and 72.90 (3)°.
منابع مشابه
[1,2-Bis(diisopropylphosphanyl)ethane-κ2 P,P′]dichloridonickel(II)–9H-carbazole (1/2)
In the title compound, [NiCl(2)(C(14)H(32)P(2))]·2C(12)H(9)N, the neutral [Ni(dppe)Cl(2)] complex [dppe is 1,2-bis-(diisopropyl-phosphan-yl)ethane] consists of a tetracoordinated Ni(2+) cation and has a crystallographic twofold axis passing through the metal atom and the mid-point of the CH(2)-CH(2) bond of the dppe ligand. The metal atom shows slight tetra-hedral distortion from an ideal squar...
متن کامل9-Benzyl-3-bromo-9H-carbazole
The title compound, C(19)H(14)BrN, was synthesized by the N-alkyl-ation of (chloro-meth-yl)benzene with 3-bromo-9H-carbazole. The carbazole ring system is essentially planar (r.m.s. deviation = 0.013 Å) and forms a dihedral angle of 87.1 (2)° with the phenyl ring.
متن کاملTriphenylsilyl- and trityl-substituted carbazole-based host materials for blue electrophosphorescence.
Carbazole-based materials adopting the nonconjugated substitution of triphenylsilyl (-SiPh(3)) and trityl (-CPh(3)) side groups are studied as high-triplet-energy, morphologically, and electrochemically stable host materials with tunable carrier-transport properties for organic blue electrophosphorescence. The developed host materials 9-(4-tert-butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole ...
متن کامل3-Bromo-9-(4-chlorobenzyl)-9H-carbazole
The title compound, C(19)H(13)BrClN, was synthesized by N-alkyl-ation of 4-chloro-1-(chloro-meth-yl)benzene with 3-bromo-9H-carbazole. The carbazole ring system is essentially planar, with a mean deviation of 0.028 Å, and it makes a dihedral angle of 91.2 (3) Å with the plane of the benzene ring.
متن کامل3,6-Dibromo-9-(4-chlorobenzyl)-9H-carbazole
The title compound, C(19)H(12)Br(2)ClN, was synthesized by N-alkyl-ation of 1-chloro-4-(chloro-meth-yl)benzene with 3,6-dibromo-9H-carbazole. The carbazole ring system is essentially planar (mean deviation of 0.028 Å) and makes a dihedral angle of 74.6 (3)° with the plane of the benzene ring.
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013