Dynamic interactions between fast microscale rotors.

نویسندگان

  • Yang Wang
  • Shih-to Fei
  • Young-Moo Byun
  • Paul E Lammert
  • Vincent H Crespi
  • Ayusman Sen
  • Thomas E Mallouk
چکیده

Trimetallic catalytic microrotors were fabricated by electrodeposition of cylindrical Au-Ru rods in the pores of anodic alumina membranes, dissolution of the template membrane, and then sequential vapor deposition of Cr, SiO(2), Cr, Au, and Pt on one side of each rod. This design provides two force vectors for the catalytic motor, including one perpendicular to the rod axis. The rods rotated rapidly (approximately 180 rpm) in 15% aqueous H(2)O(2) solution with minimal orbital or translational movement. The rotation was rapid enough to observe qualitatively different interactions between pairs of co- and counter-rotating rods. Counter-rotating rods were able to approach each other closely and underwent frequent tip-to-tip collisions. Co-rotating rods could approach each other only to a distance of approximately 0.9 microm. This difference is rationalized on the basis of shear forces generated by the catalytically driven rotation of the rods.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Dynamic self-assembly of microscale rotors and swimmers.

Biological systems often involve the self-assembly of basic components into complex and functioning structures. Artificial systems that mimic such processes can provide a well-controlled setting to explore the principles involved and also synthesize useful micromachines. Our experiments show that immotile, but active, components self-assemble into two types of structure that exhibit the fundame...

متن کامل

Flow Seals Parameters Analysis For Rotors

The interaction of work fluid mechanics with that of the rotary system itself, basically composed of axes, bearings and rotors, is performed by inserting equivalent dynamic coefficients in the mathematical model of the rotor, the latter being obtained by the finite element method. In this paper, the dynamic coefficients of inertia, stiffness and damping of the flat seals analyzed here are evalu...

متن کامل

Orienting coupled quantum rotors by ultrashort laser pulses

We point out that the non-adiabatic orientation of quantum rotors, produced by ultrashort laser pulses, is remarkably enhanced by introducing dipolar interaction between the rotors. This enhanced orientation of quantum rotors is in contrast with the behavior of classical paired rotors, in which dipolar interactions prevent the orientation of the rotors. We demonstrate also that a specially desi...

متن کامل

ATLAS: A Geometric Approach to Learning High-Dimensional Stochastic Systems Near Manifolds

When simulating multiscale stochastic differential equations (SDEs) in high-dimensions, separation of timescales, stochastic noise and high-dimensionality can make simulations prohibitively expensive. The computational cost is dictated by microscale properties and interactions of many variables, while the behavior of interest often occurs at the macroscale level and at large time scales, often ...

متن کامل

Tuning-up and driving a redox-active rotor.

The dynamic bistable rotational behaviour of a copper(I) coordination environment can be rationally tuned with balancing the substituent size on the rotor. Such rotors are sensitive to weak interactions, and the rotation was driven by a redox reaction on a ferrocenyl moiety via reconstruction of the charge interaction between redox centres.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 131 29  شماره 

صفحات  -

تاریخ انتشار 2009