Crystal structure of catena-poly[[tri­methyl­tin(IV)]-μ-2-(2-nitro­phen­yl)acetato-κ2 O:O′]

نویسندگان

  • Muhammad Danish
  • Muhammad Nawaz Tahir
  • Sana Iftikhar
  • Muhammad Asam Raza
  • Muhammad Ashfaq
چکیده

In the title one-dimensional coordination polymer, [Sn(CH3)3(C8H6NO4)] n , the Sn(IV) atom is coordinated by three methyl C atoms and two carboxyl-ate O atoms (one symmetry generated), resulting in an almost regular SnC3O2 trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 21 screw axis. A weak π-π inter-action exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å.

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عنوان ژورنال:

دوره 71  شماره 

صفحات  -

تاریخ انتشار 2015