A donor-functionalized, silyl-substituted pentadienyllithium: structural insight from experiment and theory.
نویسندگان
چکیده
A donor-functionalized, silyl-substituted pentadienyllithium has been synthesized and characterized by crystallography and NMR spectroscopy. The pentadienyl negative charge was found to be partially localized, which DFT revealed to be due to the polarizing power of the lithium cation.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 47 21 شماره
صفحات -
تاریخ انتشار 2011