Mechanism of resonant electron emission from the deprotonated GFP chromophore and its biomimetics† †Electronic supplementary information (ESI) available: Experimental and computational details, calculated VEEs in anions and radicals, orbitals involved in electronic transitions, detailed discussion of direct and resonant spectral shapes, mechanism of vibrational autodetachment out of S1 above the S1/D0 crossing, impact of the substituents, and coordinates of the optimized structures. See DOI: 10.1039/c6sc05529j Click here for additional data file.

A genomics-led approach to deciphering the mechanism of thiotetronate antibiotic biosynthesis† †Electronic supplementary information (ESI) available: Fig. S1–S21; Tables S1–S5, full experimental details and procedures. See DOI: 10.1039/c5sc03059e Click here for additional data file.

Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion† †Electronic supplementary information (ESI) available: Preparation and physical characterization data of 1P and 2M, additional structural description, UV-Vis and CD spectra (Fig. S1–S7), crystallographic refinement details for 1P and 2M (Table S1), selected bond distances and angles for 1P and 2M (Tables S2–S5), ESI(+)-MS and ESI(+)-MSMS spectra (Fig. S8–S11 and Schemes S1 and S2) and PXRD (Fig. S12). CCDC 1046609 and 1046610. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01089f Click here for additional data file. Click here for additional data file.

Conducting polyfurans by electropolymerization of oligofurans† †This work is dedicated to the memory of Professor Michael Bendikov. ‡ ‡Electronic supplementary information (ESI) available: Full experimental and computational details, synthesis of 1–18, Fig. S1–S26 and Tables S1–S4. See DOI: 10.1039/c4sc02664k Click here for additional data file.

Optical and electronic properties of air-stable organoboron compounds with strongly electron-accepting bis(fluoromesityl)boryl groups† †Electronic supplementary information (ESI) available: Experimental details. Additional views of the molecular structures from X-ray diffraction. Cyclic voltammograms of 2 and 3. Plots of calculated lowest energy transitions versus UV-visible absorption spectra. Variable-temperature emission and excitation spectra. Copies of all NMR spectra. Cartesian coordinates of all optimised geometries. CCDC 1010408–1010412. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02410a Click here for additional data file. Click here for additional data file.

Institut für Anorganische Chemie, Julius Hubland, 97074 Würzburg, Germany. E-ma School of Medicine, Pharmacy and Health, Stockton-on-Tees, TS17 6BH, UK Department of Chemistry, University of Tor M5S 3H6, Canada Institut für Organische Chemie, JuliusHubland, 97074 Würzburg, Germany † Electronic supplementary information Additional views of the molecular stru voltammograms of 2 and 3. Plots of ca...

The origin of the ligand-controlled regioselectivity in Rh-catalyzed [(2 + 2) + 2] carbocyclizations: steric vs. stereoelectronic effects† †Electronic supplementary information (ESI) available: Computational details, Cartesian coordinates and vibrational frequencies of all optimized structures. See DOI: 10.1039/c5sc02307f Click here for additional data file.

Department of Chemistry, Indiana Universi 47405, USA. E-mail: [email protected] Department of Chemistry, Queen's Universit Canada. E-mail: [email protected] Department of Chemistry, Korea Advanced I Daejeon, 305-701, South Korea Center for Catalytic Hydrocarbon Functiona Daejeon, 305-701, South Korea † Electronic supplementary information Cartesian coordinates and vibrational fr See DOI: ...