1,1′-Bis(3-methyl-3-phenylcyclobutyl)-2,2′-(azanediyl)diethanol
نویسندگان
چکیده
The title mol-ecule, C(26)H(35)NO(2), contains two cyclo-butane rings that adopt butterfly conformations and are linked by a -CH(OH)CH(2)NHCH(2)CH(OH)- bridge. In the crystal, N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds together with C-H⋯π inter-actions link the molecules.
منابع مشابه
2,2′-{[4,6-Bis(octylamino)-1,3,5-triazin-2-yl]azanediyl}diethanol
In the title compound, C(23)H(46)N(6)O(2), the two hy-droxy groups are located on opposite sides of the triazine ring. One of the hy-droxy groups links with the triazine N atom via an intra-molecular O-H⋯N hydrogen bond. Inter-molecular O-H⋯N and N-H⋯O hydrogen bonding is observed in the crystal structure. π-π stacking is also observed between parallel triazine rings of adjacent mol-ecules, the...
متن کامل[2,2′-(1,1′-Binaphthyl-2,2′-diyldiimino)diethanol-κ3 N,N′,O]dichloridocopper(II)
In the title complex, [CuCl(2)(C(24)H(24)N(2)O(2))], the Cu(II) cation is N,N',O-chelated by a 2,2'-(1,1'-binaphthyl-2,2'-diyldiimino)-diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twisted with respect to each other at a dihedral angle of 68.30 (9)°. The uncoord-inated hy-droxy grou...
متن کاملDichloro-2,2-bis(p-chlorophenyl)ethane, and 1-Chloro-2,2-bis(p- chlorophenyl)ethene in the Hamster1
The urinary metabolites of 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane (DDT), 1,1-dichloro-2,2-bis(p-chlorophenyl)ethane (ODD), and 1-chloro-2,2-bis(p-chlorophenyl)ethene in female hamsters are reported. The principal metabolite of both DDT and ODD is 2,2-bis(p-chlorophenyl) acetic acid. DDTand DDDtreated animals also excreted small amounts of DDD, 1-chloro2,2-bis(p-chlorophenyl)ethene, 1,1 -...
متن کاملNew thermoplastic poly(carbonate-urethane)s based on chain extenders with sulfur atoms
New thermoplastic segmented polyurethanes were obtained by a one-step melt polyaddition using 40, 50 and 60 mol% poly(hexane-1,6-diyl carbonate) diol of [Formula: see text] g mol-1, 1,1'-methanediylbis(4-isocyanatobenzene) and 2,2'-[sulfanediylbis(benzene-1,4-diyloxy)]diethanol, 2,2'-[oxybis(benzene-1,4-diylsulfanediyl)]diethanol or 2,2'-[sulfanediylbis(benzene-1,4-diylsulfanediyl)]diethanol as...
متن کامل2,2′-Bis(methoxymethoxy)-3-methyl-1,1′-binaphthyl
The title compound, C(25)H(24)O(4), a meth-oxy-methyl (MOM) bis-protected BINOL derivative containing a methyl substituent in position 3, is a key inter-mediate for the synthesis of a great variety of chiral auxiliaries. The planes of the naphthyl aromatic rings are at an angle of 70.74 (3)°. There are no conventional hydrogen bonds binding the mol-ecules.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012