Poly[[bis(μ2-4,4′-bipyridine)[μ2-(2,4-dichlorophenoxy)acetato]copper(I)] nitrate]
نویسنده
چکیده
The title compound, {[Cu(2)(C(8)H(5)Cl(2)O(3))(C(10)H(8)N(2))(2)]NO(3)}(n) was prepared by reacting copper(II) nitrate with 4,4'-bipyridine (4,4'-bipy) and (2,4-dichloro-phen-oxy)acetic acid under solvothermal conditions. Each of two copper(I) atoms in the asymmetric unit is three-coordinated by two N atoms from two 4,4'-bipy ligands and one O atom from the (2,4-dichloro-phen-oxy)acetate ligand. As both ligands act as bridging ligands, a double-stranded chain structure is observed.
منابع مشابه
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متن کاملPoly[bis(μ2-4,4′-bipyridine)bis(3-nitrobenzoato)nickel(II)]
The crystal structure of the title complex, [Ni(C(7)H(4)NO(4))(2)(C(10)H(8)N(2))(2)](n), exhibits a two-dimensional network, which is built up from slightly distorted NiN(4)O(2) polyhedra (2 symmetry), bipyridine ligands, and carboxyl-ate anions. The Ni(II) atoms are six-coordinated by two O atoms of two monodentate carboxyl-ate anions and four N atoms from bipyridine ligands and are connected ...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010