5-Cyclohexyl-2-(4-fluorophenyl)-3-phenylsulfinyl-1-benzofuran
نویسندگان
چکیده
The asymmetric unit of the title compound, C26H23FO2S, contains two independent mol-ecules (A and B), in both of which the cyclo-hexyl ring adopts a chair conformation. The benzo-furan ring systems, the 4-fluoro-phenyl and phenyl rings are essentially planar, with r.m.s. deviations of 0.008 (1), 0.002 (1) and 0.003 (1) Å, respectively, for mol-ecule A, and 0.016 (1), 0.004 (1) and 0.002 (1) Å, respectively, for mol-ecule B. The dihedral angles between the benzo-furan ring system and the pendant 4-fluoro-phenyl and phenyl rings are 12.3 (7) and 85.42 (4)°, respectively, for mol-ecule A, and 39.67 (6) and 72.17 (4)°, respectively, for mol-ecule B. In the crystal, mol-ecules are linked by weak C-H⋯O and C-H⋯π inter-actions, resulting in a three-dimensional network.
منابع مشابه
5-Fluoro-2-(4-fluorophenyl)-7-methyl-3-phenylsulfinyl-1-benzofuran
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متن کامل5-Cyclohexyl-2-(2-fluorophenyl)-3-methylsulfinyl-1-benzofuran
In the title compound, C21H21FO2S, the cyclo-hexyl ring adopts a chair conformation. The 2-fluoro-benzene ring makes a dihedral angle of 38.68 (6)° with the mean plane [r.m.s. deviation = 0.018 (2) Å] of the benzo-furan fragment. In the crystal, mol-ecules are linked by pairs of C-H⋯O hydrogen bonds into dimers, which are further packed into stacks along the c axis by C-H⋯O hydrogen bonds. In a...
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013