Towards conformationally-locked difluorosugar analogues: an unexpected sense of dihydroxylation.
نویسندگان
چکیده
Difluorinated cyclooctenones, synthesised using RCM, can be used as templates for stereoselective oxidative transformations to products that undergo transannular reactions to afford conformationally-locked analogues of 2-deoxy-2,2-difluorosugars with different stereochemical relationships between the C-2 and C-3 hydroxyl groups.
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عنوان ژورنال:
- Chemical communications
دوره 3 شماره
صفحات -
تاریخ انتشار 2004