1 4 Ju n 20 05 1 High field properties of geometrically frustrated magnets

Above the saturation field, geometrically frustrated quantum antiferromagnets have dispersionless low-energy branches of excitations corresponding to localized spin-flip modes. Transition into a partially magnetized state occurs via condensation of an infinite number of degrees of freedom. The ground state below the phase transition is a magnon crystal, which breaks only translational symmetry and preserves spin-rotations about the field direction. We give a detailed review of recent works on physics of such phase transitions and present further theoretical developments. Specifically, the low-energy degrees of freedom of a spin-1/2 kagomé antiferromagnet are mapped to a hard hexagon gas on a triangular lattice. Such a mapping allows to obtain a quantitative description of the magnetothermodynamics of a quantum kagomé antiferromagnet from the exact solution for a hard hexagon gas. In particular, we find the exact critical behavior at the transition into a magnon crystal state, the universal value of the entropy at the saturation field, and the position of peaks in temperatureand field-dependence of the specific heat. Analogous mapping is presented for the sawtooth chain, which is mapped onto a model of classical hard dimers on a chain. The finite macroscopic entropies of geometrically frustrated magnets at the saturation field lead to a large magnetocaloric effect.