Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I).
نویسندگان
چکیده
Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir-bifluoride and Ir(I)-NHC and Rh(I)-NHC trifluoromethyl complexes are revealed.
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عنوان ژورنال:
- Chemical communications
دوره 51 1 شماره
صفحات -
تاریخ انتشار 2015