Synthesis of trifluoroethoxy-coated binuclear phthalocyanines with click spacers and investigation of their clamshell behaviour.
نویسندگان
چکیده
We disclose here the synthesis of a novel trifluoroethoxy-coated binuclear Pc which is the first example of a never-closing clamshell Pc.
منابع مشابه
Synthesis and properties of trifluoroethoxy-coated binuclear phthalocyanine.
A genuine example of non-aggregated highly fluorescent binuclear phthalocyanines is reported; spectroscopic studies and computations revealed that the two halves of trifluoroethoxy-coated binuclear phthalocyanine are rotated in the same directions so as to contact each other as much as possible.
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A novel covalently linked binuclear phthalocyanine 1 was synthesized by the "double-click" reaction. The UV-vis and fluorescence spectra and electrochemistry revealed that the geometry of 1 is a closed clamshell conformation in which a strong electronic interaction is observed between the two Pc moieties.
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عنوان ژورنال:
- Organic & biomolecular chemistry
دوره 7 11 شماره
صفحات -
تاریخ انتشار 2009