Aqua(9,10-dioxoanthracene-1,5-disulfonato-κO 1)bis(1,10-phenanthroline-κ2 N,N′)nickel(II)
نویسنده
چکیده
In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octa-hedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the other from a water mol-ecule. An intra-molecular O-H⋯O hydrogen bond occurs. In the crystal, inter-molecular O-H⋯O hydrogen bonds link the mononuclear complexes into chains extending parallel to [010]. Furthermore, π-π stacking inter-actions [centroid-centroid distance = 3.5696 (6) Å] stabilize the crystal structuure.
منابع مشابه
catena-Poly[[[bis(1,10-phenanthroline-κ2 N,N′)manganese(II)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ2 O 1:O 5] tetrahydrate]
The title complex, {[Mn(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)]·4H(2)O}(n), exhibits a chain-like polymeric structure with 9,10-dioxo-anthracene-1,5-disulfonate anions bridging Mn(II) atoms in a bis-monodentate mode. The unique Mn(II) atom is located on a crystallographic centre of inversion. Four N atoms from two chelating 1,10-phenanthroline ligands and two sulfonate O atoms from two symmetry-r...
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In the title compound, [Co(C(5)H(9)O(2))(2)(C(12)H(8)N(2))(H(2)O)], the Co(II) atom is coordinated in a distorted octahedral environment by three carboxyl O atoms of two trimethyl-acetate ligands, one aqua O atom and two N atoms from 1,10-phen-anthroline. The crystal structure is stabilized by O-H⋯O hydrogen bonds and π-π stacking inter-actions [inter-planar distance between inter-digitating 1,...
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The title compound, [Pb(2)(C(7)H(5)O(2))(2)(NO(3))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)], crystallizes as a dinuclear centrosymmetric dimer containing two Pb(II) atoms bridged by two benzoate ligands. Each Pb(II) atom is seven-coordinated by a water mol-ecule, a nitrate anion, a 1,10-phenanthroline (phen) ligand and two benzoate anions. The crystal packing is stabilized by O-H⋯O hydrogen bonds and by...
متن کاملAqua(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)bis(3-hydroxybenzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1)
In the title compound, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·H(2)O, the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two monodentate 3-hydroxy-benzoate anions (3-HBA) and one water mol-ecule in a distorted trigonal-bipyramidal environment. An uncoordinated dmphen and an uncoordinated water mol-ecule cocrystallized with each com...
متن کاملcatena-Poly[[[aqua(formato-κO)(1,10-phenanthroline-κ2 N,N′)manganese(II)]-μ-formato-κ2 O:O′] monohydrate]
The title compound, {[Mn(HCOO)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O}(n), consists of polymeric chains of the complex [Mn(HCOO)(2)(phen)(H(2)O)](∞) (phen is 1,10-phenanthroline) with solvent water mol-ecules. The chains contain six-coordinate Mn(II) ions bridged by formate anions. They are further extended into a three-dimensional network via O-H⋯O hydrogen-bonding inter-actions and inter-chain π-π s...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010