Local structures around the substituted elements in mixed layered oxides
نویسندگان
چکیده
The chemical substitution of a transition metal (M) is an effective method to improve the functionality of a material, such as its electrochemical, magnetic, and dielectric properties. The substitution, however, causes local lattice distortion because the difference in the ionic radius (r) modifies the local interatomic distances. Here, we systematically investigated the local structures in the pure (x = 0.0) and mixed (x = 0.05 or 0.1) layered oxides, Na(M1-xM'x)O2 (M and M' are the majority and minority transition metals, respectively), by means of extended X-ray absorption fine structure (EXAFS) analysis. We found that the local interatomic distance (dM-O) around the minority element approaches that around the majority element to reduces the local lattice distortion. We further found that the valence of the minority Mn changes so that its ionic radius approaches that of the majority M.
منابع مشابه
Dynamic Analysis of Cylindrically Layered Structures Reinforced by Carbon Nanotube Using MLPG Method
This paper deals with the dynamic analysis of stress field in cylindrically layeredstructures reinforced by carbon nanotube (CLSRCN) subjected to mechanical shock loading.Application of meshless local integral equations based on meshless local Petrov-Galerkin(MLPG) method is developed for dynamic stress analysis in this article. Analysis is carriedout in frequency domain by applying the Laplace...
متن کاملThe iron oxidation state in Mg–Al–Fe mixed oxides derived from layered double hydroxides: An XPS study
Mixed oxides with large surface area and high thermal stability can be obtained by thermal treatment of the layered double hydroxides (LDH). Mg–Al–Fe mixed oxide samples with varying Mg/Al ratio and 5 mol.% of Fe were prepared in this way and the iron oxidation state (Feox) in these compounds was studied by X-ray photoelectron spectroscopy (XPS), using a calibration based on the relation of Feo...
متن کاملExploring Li substituted O3-structured layered oxides NaLixNi1/3−xMn1/3+xCo1/3−xO2 (x=0.07, 0.13, and 0.2) as promising cathode materials for rechargeable Na batteries
متن کامل
Recent research progress on iron- and manganese-based positive electrode materials for rechargeable sodium batteries
Large-scale high-energy batteries with electrode materials made from the Earth-abundant elements are needed to achieve sustainable energy development. On the basis of material abundance, rechargeable sodium batteries with iron- and manganese-based positive electrode materials are the ideal candidates for large-scale batteries. In this review, iron- and manganese-based electrode materials, oxide...
متن کاملFirst principles studies on band structures and density of states of graphite surface oxides
Graphite oxide constitutes carbon network with oxygen atoms both on hexagonal arrangement and the edge sites. Structural and electronic properties for graphite-oxygen complexes have been explored using first-principles total-energy calculations within the local density approximation (LDA). Band structures and density of states for the propose carbon 3D models are reported. A finite energy gap and...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 7 شماره
صفحات -
تاریخ انتشار 2017