catena-Poly[[copper(II)-bis[μ-bis(pyridin-3-yl)methanone-κ2 N:N′]] bis(tetrafluoridoborate)]
نویسنده
چکیده
In the title complex, {[Cu(C(11)H(8)N(2)O)(2)](BF(4))(2)}(n), the Cu(II) ion is situated on an inversion centre and adopts an N(4)F(2) octa-hedral coordination geometry with four N atoms from four different bis-(pyridin-3-yl)methanone ligands at the equatorial sites and two independent tetra-fluoridoborate anions weakly bonded at the axial sites via two F atoms [Cu⋯F = 2.613 (3) Å]. Chains with the bridging ligands are formed along the a axis. C-H⋯F inter-actions stabilize the structure. C-O⋯π inter-actions also occur.
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011