catena-Poly[[[N,N′-bis(3-methoxybenzylidene)ethylenediamine]copper(I)]-μ-thiocyanato-κ2 N:S]
نویسندگان
چکیده
In the cyrstal structure of the title compound, [Cu(NCS)(C(18)H(20)N(2)O(2))](n), the Cu(I) atom is coordinated in a distorted tetra-hedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thio-cyanate anions. The thio-cyanate anion bridges the Cu(I) atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.
منابع مشابه
catena-Poly[[(1,10-phenanthroline-κ2 N,N′)copper(I)]-μ-thiocyanato-κ2 N:S]
In the title complex, [Cu(NCS)(C(12)H(8)N(2))](n), the Cu(I) ion is in a distorted tetra-hedral CuN(3)S coordination geometry. The thio-cyanate ligand acts as bridging ligand, forming chains along [100]. A crystallographic mirror plane runs through the Cu(I) ion, the thio-cyanate ligand and the middle of the phenanthroline ligand.
متن کاملcatena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ2 N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ2 N:S]
In the title one-dimensional coordination polymer, [Mn(NCS)(3)(C(10)H(16)N(3))](n), the Mn(II) atom is coordinated by an N,N'-bidentate Schiff base and four thio-cyanate ligands in a distorted octa-hedral N(5)S geometry. Bridging thio-cyanate ligands inter-connect adjacent [Mn(NCS)(2)(C(10)H(16)N(3))] units, giving rise to helical chains extending along the b axis. The chains are further linked...
متن کاملcatena-Poly[hemi{bis[4′-(3-pyridyl)-2,2′:6′,2′′-terpyridine-κ3 N 1,N 1′,N 1′′]copper(II)} [cuprate(I)-di-μ2-thiocyanato-κ2 N:S;κ2 S:N]]
The title compound, {[Cu(C(20)H(14)N(4))(2)][Cu(2)(NCS)(4)]}(n), was obtained by reacting copper acetate hydrate, ammonium thio-cyanate and 4'-(3-pyrid-yl)-2,2':6',2''-terpyridine (3-pytpy) under solvothermal conditions. The polymeric complex is isostructural with the 4'-phenyl-2,2':6',2''-terpyridine (phtpy) analogue. All intramolecular distances and angles are very similar for the two structu...
متن کاملcatena-Poly[[bis[2-(1H-1,2,4-triazol-1-yl-κN 4)pyrazine]cadmium(II)]-di-μ-thiocyanato-κ2 S:N;κ2 N:S]
The title compound, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), is a coordination polymer with the Cd(II) centre located on a twofold rotation axis. The Cd(II) centre assumes a distorted octa-hedral geometry. The thio-cyanate anions function as bridging ligands between the Cd(II) centres, leading to a chain-like arrangement expanding along [001].
متن کاملcatena-Poly[[bis(2-methoxyaniline-κN)cadmium]-di-μ-thiocyanato-κ2 N:S;κ2 S:N]
The structure of the title compound, [Cd(NCS)2(C7H9NO)2] n , consists of cadmium-thio-cyanate layers parallel to the ab plane. Pairs of Cd(II) ions are bridged by two end-to-end inversely bridging μ-NCS-N:S thio-cyanate groups, forming a two-dimensional network with the remaining two trans positions of the octa-hedrally coordinated Cd(II) ions occupied by the N atoms of two neutral 2-meth-oxy-a...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2008