Molecular Interaction Studies in Binary Liquid Mixtures Using Ultrasonic Techniques

Recently Khasare derived an equation of state for L-J fluid by modifying an expression for work done, obtained from partition function through perturbation approach .This is achieved by inserting at some fixed position in the m-component fluid, a single solute particle of radius ‘R’ in n-dimensions along with the necessary thermodynamic requirements. It was therefore thought worthwhile to undertake a comprehensive investigation of Khasare’s is equation of state for real fluid as regards its applicability to various real fluids mixtures and capacity to predict thermodynamic behaviour in them .The theory has been applied to such binary liquid mixture systems which consists of different spatial arrangements of hard spheres solutes or solvent molecules at the same time are either polar or non-polar molecules in different environments.