catena-Poly[bis(μ4-adipato-1:2:1′:2′κ4 O 1:O 1′:O 4:O 4′)bis(N,N-dimethylformamide)-1κO,2κO-dicopper(II)]
نویسندگان
چکیده
In the title polymeric complex, [Cu(2)(C(6)H(8)O(4))(2)(C(3)H(7)NO)(2)](n), the carboxyl-ate groups of the approximately U-shaped adipate dianion each bridge a pair of inversion-related, DMF-coordinated copper(II) atoms, generating a ribbon motif that runs along the b axis. The geometry of the copper(II) atom is distorted square-pyramidal; the apical site is occupied by the O atom of the DMF mol-ecule whereas the four basal sites are occupied by carboxyl-ate O atoms.
منابع مشابه
Poly[bis(N,N-dimethylacetamide)-1κO,2κO-bis(μ4-thiophene-2,5-dicarboxylato-1:2:1′:2′κ4 O 2:O 2′:O 5:O 5′)dizinc]
In the title polymeric complex, [Zn(2)(C(6)H(2)O(4)S)(2)(C(4)H(9)NO)(2)](n), each carboxyl-ate group of the thio-phene-2,5-dicarboxyl-ate dianion bridges a pair of inversion-related dimethyl-acetamide-coordinated Zn(II) atoms, generating a layer motif parallel to (101). The Zn(II) atom shows a distorted square-pyramidal coordination; the apical site is occupied by the O atom of the dimethyl-ace...
متن کاملcatena-Poly[hexaaqua-1κO,2κO,3κ4 O-(μ4-3,5-dicarboxylatopyrazol-1-ido-3′:1:2:3κ6 O 5:N 1,O 5′:N 2,O 3:O 3′)(μ2-3,5-dicarboxylatopyrazol-1-ido-1:2κ4 N 2,O 3:N 1,O 5)-1,2-dicopper(II)-3-manganese(II)]
In the title compound, [Cu(2)Mn(C(5)HN(2)O(4))(2)(H(2)O)(6)](n), the Cu(II) ion is coordinated by two N atoms, two O atoms and one water O atom in a distorted square-pyramidal geometry. The Mn(II) ion is coordinated by two O atoms and four water O atoms in a distorted octa-hedral geometry. Two pyrazolyl-3,5-dicarboxyl-ate anions chelate to two copper ions, forming a dinuclear unit, which furthe...
متن کاملcatena-Poly[[bis(N,N-dimethylformamide-κO)zinc]-μ2-oxalato-κ4 O 1,O 2:O 1′,O 2′]
In the crystal structure of the title compound, [Zn(C(2)O(4))(C(3)H(7)NO)(2)](n), the Zn(II) ion is situated on a twofold rotation axis and has a distorted octa-hedral coordination geometry defined by the O atoms of two dimethyl-formamide mol-ecules and four O atoms of two bidentate oxalate ligands. The oxalate anion is located on an inversion centre and bridges two metal ions, resulting in a p...
متن کاملPoly[di-μ5-adipato-κ4 O:O′:O′′:O′′′,O′′′-μ4-adipato-κ4 O:O′:O′′:O′′′-bis[2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2 N 7,N 8]tricobalt(II)]
In the title polymer, [Co(3)(C(6)H(8)O(4))(3)(C(19)H(12)N(4))(2)](n), two adipate dianions (C(6)H(8)O(4) (2-)) occupy general positions and two are situated on different inversion centres. The two on general positions bind through their four O atoms to five 2-phenyl-1H-1,3,7,8-tetra-azacyclo-penta-[l]phenanthrene-chelated Co(II) ions, whereas the two on special positions bind to only four. Of t...
متن کاملcatena-Poly[[bis(dimethylammonium) [cadmate(II)-bis(μ-1,1′:4′,1′′-terphenyl-3,3′′-dicarboxylato)]] dimethylformamide disolvate]
In the title compound, {(C(2)H(8)N)(2)[Cd(C(20)H(12)O(4))(2)]·2C(3)H(7)NO}(n), the Cd(II) ion lies on a twofold rotation axis and is in a distorted octa-hedral CdO(6) environment, defined by four O atoms of two μ(2)-coordinated 1,1':4',1''-terphenyl-3,3''-dicarboxyl-ate (DCT) ligands and two O atoms of two μ(1)-coordinated DCT ligands. Both types of DCT ligands act as bridging, forming a one-di...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010