Electrochemical Investigation of Mo(VI)-MTB-ClO-3 System in Phosphate Buffer

Authors

  • Afsaneh Safavi Department of Chemistry, College of Sciences, Shiraz University, Shiraz 71454, I.R. IRAN
  • Esmaeil Shams Department of Chemistry, College of Sciences, Shiraz University, Shiraz 71454, I.R. IRAN
Abstract:

The reduction mechanism of molybdenum-methyl thymol blue (MTB)-chlorate system has been investigated in water on a mercury electrode. As this system is very sensitive for ultratrace determination of molybdenum, the actual mechanism involved was studied. Electrochemical techniques, including dc tast polarography and cyclic voltammetry were employed. It is shown that, the cathodic wave of molybdenum in the presence of methyl thymol blue and chlorate has an adsorptive catalytic character. 

Upgrade to premium to download articles

Sign up to access the full text

Already have an account?login

similar resources

electrochemical investigation of mo(vi)-mtb-clo-3 system in phosphate buffer

the reduction mechanism of molybdenum-methyl thymol blue (mtb)-chlorate system has been investigated in water on a mercury electrode. as this system is very sensitive for ultratrace determination of molybdenum, the actual mechanism involved was studied. electrochemical techniques, including dc tast polarography and cyclic voltammetry were employed. it is shown that, the cathodic wave of molybde...

full text

investigation of (meta)discourse markers in elt coursebooks

the present study aimed to investigate representation of discourse markers and metadiscourse markers in conversations and readings of general elt coursebook series used in the language centers of iran. to this aim, four elt coursebooks popularly taught in language centers of this country were analyzed based on fung and carter’s (2007) framework regarding discourse markers and hyland’s (2005) fr...

synthesis of platinum nanostructures in two phase system

چکیده پلاتین، فلزی نجیب، پایدار و گران قیمت با خاصیت کاتالیزوری زیاد است که کاربرد های صنعتی فراوانی دارد. کمپلکس های پلاتین(ii) به عنوان دارو های ضد سرطان شناخته شدند و در شیمی درمانی بیماران سرطانی کاربرد دارند. خاصیت کاتالیزوری و عملکرد گزینشی پلاتین مستقیماً به اندازه و- شکل ماده ی پلاتینی بستگی دارد. بعضی از نانو ذرات فلزی در سطح مشترک مایع- مایع سنتز شده اند، اما نانو ساختار های پلاتین ب...

Multielectrode Teflon electrochemical nanocatalyst investigation system

The most common approach in the search for the optimal low temperature fuel cell catalyst remains "trial and error". Therefore, large numbers of different potential catalytic materials need to be screened. The well-established and most commonly used method for testing catalytic electrochemical activity under well-defined hydrodynamics is still thin film rotating disc electrode (TF-RDE). Typical...

full text

Investigation of H Pylori Colonization in Adenotonsillectomy Specimens by Means of Rapid Urease (CLO) Test

This prospective clinical study was performed to investigate the colonization of H pylori in adenoid and tonsil tissues by using the Campylobacter-like organism (CLO) test. Included in the study were 56 patients aged 3 to 43 yrs who had undergone adenoidectomy, tonsillectomy or adenotonsillectomy procedures under general anesthesia. Two-mm diameter tissue pieces of adenoid and tonsil specimens ...

full text

My Resources

Save resource for easier access later

Save to my library Already added to my library

{@ msg_add @}


Journal title

volume 20  issue 2

pages  96- 101

publication date 2001-12-01

By following a journal you will be notified via email when a new issue of this journal is published.

Hosted on Doprax cloud platform doprax.com

copyright © 2015-2023