Keggin-Type Heteropolyacids-Catalyzed One Pot Oxidation-Trimerization of Alcohols into 2,4,6-Trisubstituted-1,3,5-Trioxanes

Authors

  • Fatemeh Bamoharram Department of Chemistry, Islamic Azad University, Mashhad Branch, Mashhad, I.R. IRAN
  • Hossein Abdi Oskooie Department of Chemistry, School of Science, Alzahra University, Tehran, I.R. IRAN
  • M. Majid Heravi Department of Chemistry, School of Science, Alzahra University, Tehran, I.R. IRAN
  • Rahim Hekmatshoar Department of Chemistry, School of Science, Alzahra University, Tehran, I.R. IRAN
  • Sodeh Sadjadi Department of Chemistry, School of Science, Alzahra University, Tehran, I.R. IRAN
Abstract:

 The catalytic air oxidation-trimerization of alcohols was carried out with hetropolyacids. In the presence of hetropolyacid formation of cyclotrimers of alcohols and aldol condensation products was observed. The 1,3,5-trioxanes were major and aldol condensation compounds were minor products.

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Journal title

volume 28  issue 2

pages  131- 136

publication date 2009-06-01

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