Reaction of Sodium Azide with 1,1'–Dicyclohexenyl–Diepoxides

Authors

  • Abolfazl Olyai Department of Chemistry, Faculty of Science, University of Tehran, Tehran, I.R. IRAN
  • Akbar Shabanikia Department of Chemistry, Faculty of Science, University of Tehran, Tehran, I.R. IRAN
  • Dariush Farkhani Research Institute of Petroleum Industry, National Iranian Oil Company, Tehran, I.R. IRAN
Abstract:

Nucleophilic ring opening of dl and meso 1,1¢- dicyclohexenyl diepoxides by sodium azide in dioxane and aqueous alcoholic medium give the corresponding azidoalcohols. The obtention of departure diepoxides from diazidoalcohols by the reaction with sodium hydride shows the anti position of OH and N3 groups.

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Journal title

volume 22  issue 2

pages  49- 53

publication date 2003-12-01

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