Central Composite experimental design applied to removal of phenanthrene and acenaphthene from soil samples

نویسندگان

  • Ebadia, Taghi aDepartment of Civil & Environmental Engineering, Amirkabir University of Technology (Tehran Polytechnic)
  • Mehdinia, Ali bDepartment of Marine Science, Iranian National Institute for Oceanography and Atmospheric Sciences, Tehran, Iran
  • Qazinezhad, Mohammad aDepartment of Civil & Environmental Engineering, Amirkabir University of Technology (Tehran Polytechnic)
چکیده مقاله:

Abstract In this work, removal of phenanthrene and acenaphthene, as a representative of polycyclic aromatic hydrocarbons, was investigated from soil samples by the soil washing remediation method combined with Central Composite Design. Response surface methodology was utilized to investigate the individual and interactive effects of three variables of removal process including surfactant solution concentration ( ), bentonite content ( ) and phenanthrene/acenaphthene solution concentration ( ). The gas chromatographic results showed that the removal efficiencies were up to 91% for phenantherene and 98% for acenaphthene. A quadratic model with high accuracy (phenantherene: R2 = 0.96, adjusted R2 = 0.94 and acenaphthene: R2 = 0.99, adjusted R2 = 0.98) was developed and well described for the removal process of phenanthrene/acenaphthene from soil. Moreover, the process was optimized to reach maximum removal scenarios. The results confirmed the accuracy and reliability of the optimization process using RSM. Therefore, response surface methodology is a suitable approach to determine the optimal parameters for chemical soil washing to remove PAH from contaminated soil by using surfactant.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

the role of russia in transmission of energy from central asia and caucuses to european union

پس ازفروپاشی شوروی،رشد منابع نفت و گاز، آسیای میانه و قفقاز را در یک بازی ژئوپلتیکی انرژی قرار داده است. با در نظر گرفتن این منابع هیدروکربنی، این منطقه به یک میدانجنگ و رقابت تجاری برای بازی های ژئوپلتیکی قدرت های بزرگ جهانی تبدیل شده است. روسیه منطقه را به عنوان حیات خلوت خود تلقی نموده و علاقمند به حفظ حضورش می باشد تا همانند گذشته گاز طبیعی را به وسیله خط لوله مرکزی دریافت و به عنوان یک واس...

15 صفحه اول

hydrochlorothiazide detection in urine samples by hplc-dad and experimental design dispersive l-l microextraction

hydrochlorothiazide (hct) is a diuretic agent which is shown to be effective in the treatment of hypertension. literature reports have demonstrated that urinary excretion data may be used to assess the bioavailability of various formulations containing this thiazide. also hct consumption by the athletes is one of the drugs which should be regulated by world anti-doping agency (wada), because of...

Central Composite Design Optimization of Zinc Removal from Contaminated Soil, Using Citric Acid as Biodegradable Chelant

Citric acid (CA) was evaluated in terms of its efficiency as a biodegradable chelating agent, in removing zinc (Zn) from heavily contaminated soil, using a soil washing process. To determine preliminary ranges of variables in the washing process, single factor experiments were carried out with different CA concentrations, pH levels and washing times. Optimization of batch washing conditions fol...

متن کامل

Comparison of central composite design and artificial neural network approaches for modeling and optimization of 2-methylpropane-2-thiol removal from contaminated soil by ultrasound

In this article a comparative study for modeling and optimization of 2-methylpropane-2-thiol removal from contaminated soil by ultrasound is investigated. Central Composite Design (CCD) and artificial neural network (ANN) were utilized and compared to each other in order to obtain appropriate predicting model with respect to sonication power (w), sonication time (min) and water/reactor volume r...

متن کامل

quantitation of nitrite in soil and water samples based on central composite design and a new griess reagent

a simple and rapid spectrophotometric method for the determination of nitrite in water and soil preparation samples has been developed. determination of nitrite is based on diazotization of p-nitro aniline with nitrite and subsequent coupling with 4-amino-3-hydroxynaphthalene-1-sulfonic acid in hydrochloric acid. the factors affecting the reaction i.e. concentration of p-nitro aniline, concentr...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ذخیره در منابع من قبلا به منابع من ذحیره شده

{@ msg_add @}


عنوان ژورنال

دوره 8  شماره 28

صفحات  81- 82

تاریخ انتشار 2017-06

با دنبال کردن یک ژورنال هنگامی که شماره جدید این ژورنال منتشر می شود به شما از طریق ایمیل اطلاع داده می شود.

کلمات کلیدی

کلمات کلیدی برای این مقاله ارائه نشده است

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023