Oxidation of greenhouse gases, CH4 and CO, over LaMnxNi1-xO3±δ mixed oxide

نویسندگان

  • Farhad Banisharif Chemical Engineering Department, School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, Iran.
  • Golshan Mazloom Department of Chemical Engineering, Faculty of Engineering, University of Mazandaran, Babolsar, Iran.
  • Mohammad Reza Dehghani Chemical Engineering Department, School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, Iran.
  • Yahya Hojatpanah Chemical Engineering Department, School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, Iran.
چکیده مقاله:

The performance of LaMnxNi1-xO3±δ perovskite mixed oxides (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9, 1) which were prepared by different methods, the Pechini and sol-gel methods in the oxidation of greenhouse gases, CH4 and CO, has been investigated. All samples were characterized using Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy and N2 adsorption. The results showed that Pechini samples are more active and stable than the sol-gel samples. The partially substituted Ni samples exhibited higher catalytic performance as compared to the LaMnO3 due to the structural defects. But, the high substitution of Ni gradually deforms the structure to rhombohedra, decreases surface area and reduces the number of active Mn sites. Therefore, the catalytic performance passes through a maximum with respect to Ni content. LaMn0.3Ni0.7O3±δ prepared by the Pechini method is more active than others in the oxidation of CH4 and CO.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Kinetics of CH4 oxidation in mixed culture.

Microbial cultures used for methane oxidation experiments were prepared by enriching under a 20 % CH4 atmosphere either leachate extracts from two different landfill sites or a digested sewage sludge. No microbes were axenically isolated, therefore the cultures were mixtures of CH4 oxidising and other aerobic microorganisms. CH4 oxidation experiments were carried out with a batch reactor, whose...

متن کامل

CO and Soot Oxidation over Ce-Zr-Pr Oxide Catalysts

A set of ceria, ceria-zirconia (Ce 80 at.%, Zr 20 at.%), ceria-praseodymia (Ce 80 at.%, Pr 20 at.%) and ceria-zirconia-praseodymia (Ce 80 at.%, Zr 10 at.% and Pr 10 at.%) catalysts has been prepared by the solution combustion synthesis (SCS). The effects of Zr and Pr as dopants on ceria have been studied in CO and soot oxidation reactions. All the prepared catalysts have been characterized by c...

متن کامل

Surface Reaction Kinetics for Oxidation and Reforming of H2, CO, and CH4 over Nickel-based Catalysts

The catalytic conversion of hydrocarbons for the production of hydrogen and syngas (H2/CO) is of great interest in research and technology. Detailed heterogeneous kinetics can also provide a better understanding of the reactions involved during the catalytic processes commonly used in the synthesis gas production. The developed models can predict conversion and selectivity at varying operation ...

متن کامل

Greenhouse Gases

Examination of research into pole alternatives indicates that, without exception, studies have found that total energy requirements associated with wood materials are considerably lower than those of commonly substituted materials. The substitution of high-energy-intensive materials for low-energy-using wood materials would contribute substantially to an overall increase in carbon

متن کامل

Effect of Ethylene Oxide Functional Groups in PEBA-CNT Membranes on CO2/CH4 Mixed Gas Separation

Poly (ether-block-amide) /poly (ethylene glycol)/ carbon nanotubes mixed matrix membranes have been successfully fabricated using solvent evaporation method to determine the effect of ethylene oxide groups on the performance of produced membranes. The effects of CNTs (2-8 wt%) and PEG (up to 50 wt%)were investigated in both single and mixed gas test setup in different temperature and pressure. ...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ذخیره در منابع من قبلا به منابع من ذحیره شده

{@ msg_add @}


عنوان ژورنال

دوره 9  شماره 4

صفحات  357- 368

تاریخ انتشار 2019-12-01

با دنبال کردن یک ژورنال هنگامی که شماره جدید این ژورنال منتشر می شود به شما از طریق ایمیل اطلاع داده می شود.

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023