Supercritical Fluid Extraction of Carotenoid from Microalgae with Projected Thermodynamic Models (RESEARCH NOTE)

نویسندگان

  • A. Zainal Chemical & Petroleum Engineering, University Science Malaysia
  • K. M. Kassim Chemical & Petroleum Engineering, University Science Malaysia
  • S. A. Sata Chemical & Petroleum Engineering, University Science Malaysia
چکیده مقاله:

In this study, two thermodynamic models (regular solution theory and equation of state) were applied to obtain carotenoid solubility in the supercritical carbon dioxide solvent. Theoretical data obtained from the models were compared with the experimental data extracted from a published paper. The use of equation of state as an empirical correlation for collating and predicting liquidliquid and liquid-dense fluid equilibrium is discussed. It is concluded that the estimation of some parameters required for these calculations would be difficult if the solute (carotenoid) was a complex substance in which little information was known, apart from its structural formula. An alternativeprocedure is to apply activity coefficient expression of the regular solution equations for each phase.Calculations along these lines are described and the physical basis for applying these methods underthe relevant conditions was also presented. The regular solution theory approach in particular hasbeen found to be encouraging for the mutual miscibility calculations for heavy components (such ascarotenoid) particularly substances that are sensitive to temperature, though the interaction parametersfor the prediction activity coefficients must be regarded as pressure dependent.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Carotenoid Pigments: Supercritical Fluid Chromatography

Carotenoids are one of the main classes of natural pigments and are found in a large number of fruits and vegetables (oranges, tomatoes, carrots) and in leaves where their presence is masked by chlorophylls until autumn. They are also found in some animal products (eggs, milk) and seafoods. Typically, carotenoids contain eight isoprenoid units bonded such that the units are reversed at the cent...

متن کامل

Supercritical Fluid Extraction+supercritical Fluid Chromatography

high pressures also requires special equipment. In summary, both RESS crystallization and SAS crystallization appear to be promising methods for generating supersaturation and therefore represent alternatives to conventional crystallization. Such alternatives may prove attractive in applications such as polymer and pharmaceutical processing, or in particle design for drug delivery. It is possib...

متن کامل

Supercritical Fluid Extraction

ganic trace analysis. Pure Applied Chemistry 55: 1943. FiReld FW and Haines PJ (1995) Environmental Analytical Chemistry. London: Chapman and Hall. Luque de CastroMD andDa Silva MP (1997) Strategies for solid sample pretreatment. Trends in Analytical Chemistry 16: 16. Luque de Castro MD and Garcia-Ayuso LE (1998) Soxhlet extraction of solid materials: an outdated techniquewith a promising innov...

متن کامل

Modeling of the Kinetics of Supercritical Fluid Extraction of Lipids from Microalgae with Emphasis on Extract Desorption

Microalgae contain valuable biologically active lipophilic substances such as omega-3 fatty acids and carotenoids. In contrast to the recovery of vegetable oils from seeds, where the extraction with supercritical CO₂ is used as a mild and selective method, economically viable application of this method on similarly soluble oils from microalgae requires, in most cases, much higher pressure. This...

متن کامل

Lipid Extraction from Wheat Flour Using Supercritical Fluid Extraction

Cereal Chem. 81(6):693–698 Environmental concerns, the disposal cost of hazardous waste, and the time required for extraction in current methods encouraged us to develop an alternate method for analysis of wheat flour lipids. Supercritical fluid extraction (SFE) with carbon dioxide has provided that medium and the method is fully automatic. Crude fats or nonstarch free lipids (FL) were extracte...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ذخیره در منابع من قبلا به منابع من ذحیره شده

{@ msg_add @}


عنوان ژورنال

دوره 21  شماره 2

صفحات  117- 126

تاریخ انتشار 2008-08-01

با دنبال کردن یک ژورنال هنگامی که شماره جدید این ژورنال منتشر می شود به شما از طریق ایمیل اطلاع داده می شود.

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023