in the present study, we investigate the potentiometric behavior of cu2+ carbon paste electrodes based on two mercapto compounds 2-ethylmino-5-mercapto-1,3,4-thiadiazole (eamt) and 2-acetylamino-5-mercapto-1,3,4-thiadiazole (aamt) self-assembled on gold nano-paricle (gnp) as ionophore. then, the results obtained from the modified electrodes are compared. the self-assembled ionophores exhibit a ...

Monitoring the acetaminophen in biological samples and also in pharmaceutical formulations is important due to the concerns of public health care and drug safety. In this work a carbon paste electrode modified with BaTiO3 nanoparticle (BTO NPs) and room-temperature ionic liquid (IL) (n-hexyl-3-methylimidazolium hexafluoro phosphate) was fabricated. The direct electro-oxidation behavior of aceta...

In this work a new chemically modified carbon paste electrode was constructed for accurate, simple, sensitive and selective determination of molybdenum (VI) ions. The results of modified electrode by an ion imprinted polymer were compared with those obtained with carbon paste electrode. The results showed the stripping peak currents had a dramatic increase at the modified electrode. Under the o...

The use of 0.6 vol.% single-walled carbon nanotubes in a poly(ethylene glycol)based dispersion gave a thermal paste that was as effective as solder for improving thermal contacts. A thermal contact conductance of 20 · 10 W m K was attained. An excessive amount of nanotubes (e.g. 1.8 vol.%) degraded the performance, because of conformability loss. The nanotubes were more effective than hexagonal...

The current-degradation mechanism of a fully sealed, carbon-nanotube field emission display is investigated experimentally and theoretically. From residual gas analysis, it is strongly evidenced that CH3 radicals from the organic materials in the paste deteriorate emission properties. Based on ab initio methods, it is found that CH3 radicals can increase electrical resistance of the nanotube an...

This paper describes the development of screen-printed (SPE) and carbon paste (CPE) sensors for the rapid and sensitive quantification of naphazoline hydrochloride (NPZ) in pharmaceutical formulations. This work compares the electroactivity of conventional carbon paste and screen-printed carbon paste electrodes towards potentiometric titration of NPZ. The repeatability and accuracy of measureme...

This article is focused on the determination of lidocaine hydrochloride as a local anaesthetic drug. A potentiometric method based on modified screen-printed and modified carbon paste ion-selective electrodes was described for the determination of lidocaine hydrochloride in different pharmaceutical preparations and biological fluids (urine and serum). It was based on potentiometric titration of...

The redox properties of sulfite ion has been examind using cyclic voltammetry in acetonitrile solvent at the surface of gold, pelatin and glassy carbon electrodes. It has bben found tha, sulfite ion exhibits two electron oxidation peak with EC’ mechanism. A novel chemically modified electrode containing Prussian blue complex and multi wall carbon nanotubes (MWCNs) was achieved on the surface of...

in the present work, an efficient modified carbon-ceramic electrode by multi-walled carbon nanotubes/ionic liquid nanocomposite (mwcnts/il/cce) was prepared through a simple and repeatable procedure. the introduced modified electrode was used for the study of the electrochemical behaviour and determination of tryptophan (trp) in the presence of uric acid (ua) using cyclic voltammetry (cv), diff...