We describe a rapid microscale procedure for blood lead determination by anodic stripping voltammetry. Results correlate well with those obtained by atomic absorption spectroscopy. The procedure involves use of a metal-exchange reagent, which rapidly releases bound lead from its macromolecular binding sites, thus eliminating a long and cumbersome perchloric acid digestion procedure. Reproducibi...

The utility of electrochemical sensors, based on stripping voltammetry, for monitoring the concentration of toxic metals in electroplating rinse tanks is described. New concepts in stripping voltammetry, based on the use of ultramicroand modified electrodes and an adsorptive preconcentration step, successfully address many of the requirements for controlling rinsewater composition. The utility ...

The influence of nanoparticle aggregation on anodic stripping voltammetry is reported. Dopamine-capped silver nanoparticles were chosen as a model system, and melamine was used to induce aggregation in the nanoparticles. Through the anodic stripping of the silver nanoparticles that were aggregated to different extents, it was found that the peak area of the oxidative signal corresponding to the...

Square-wave adsorptive cathodic stripping voltammetry was used to determine pioglitazone HCl in Britton Robinson buffer of pH5. The adsorptive cathodic peak was observed at -1.5 V vs. Ag/AgCl. The peak response was characterized with respect to pH, supporting electrolyte, frequency, scan increment, pulse-amplitude, accumulation potential and pre-concentration time. Under optimal conditions, the...

in the present work, an adsorptive stripping voltammetric method using a hanging mercurydrop electrode (hmde) was described in order to determine the ultra trace of thiosemicarbazidein different real samples. the method is based on accumulation of thiosemicarbazide on mercuryelectrode. the potential was scanned to the negative direction and the differential pulse strippingvoltammograms were rec...