a selective and sensitive method for determination of cadmium and zinc is presented. the method is based on adsorptive accumulation of the complexes of cd (ii) and zn (ii) ions with 4-amiono-5-methyl-2,4-dihydro-3h-1,2,4-triazol-3-tion (mmtt) onto hanging mercury drop electrode (hmde), followed by reduction of the adsorbed species by voltammetric scan using differential pulse modulation. the li...

This is a review of analytical methods, such as spectrophotometry, derivative spectrophotometry and various chromatographic (gas chromatography-GC, high-performance liquid chromatography-HPLC, thin-layer chromatography-TLC, high-performance thin-layer chromatography-HPTLC, liquid chromatography-tandem mass spectrometry-LC-MS, microchip electrophoresis-MCE, capillary electrophoresis-CE) and elec...

The surface activity of xanthine (Xan) and xanthosine (Xano) at a hanging mercury drop electrode (HMDE) was studied using out-of-phase ac and cyclic dc voltammetry. The results show that Xan and Xano were strongly adsorbed and chemically interacted with the charged mercury surface, which is the prerequisite step for applying the cathodic adsorptive stripping voltammetric determination of such b...

Aminophylline is determined by cathodic stripping voltammetry (CSV) in BR buffer, pH 7.5 at a hanging mercury drop electrode. The detection limit was 3x10 M after 60 s accumulation at -0.60 V versus Ag/AgCl reference electrode. The linear range demonstrated up to 5x10 M using CSV. The interference caused by some purine derivatives, anions and some metal cations on the peak current was studied. ...

A sensitive method for the determination of chitosan (CTS) by cathodic stripping voltammetry is presented. The method exploits a pair of oxidation-reduction peaks of CTS at -0.62 V (vs. SCE) and -0.54 V (vs. SCE), and an enhancement of the peak current of CTS observed in a 0.05 mol l(-1) potassium hydrogenphthalate buffer solution (pH 2.5). The peak current is linear with the concentration of C...

In this study, 2-aminobenzoic acid (ABA) has been used as complexing ligand for simultaneousdetermination of metal ions by adsorptive cathodic stripping voltammetry (AdCSV), for the firsttime. Thus, a selective and sensitive procedure was presented for simultaneous determination oflead, cadmium and nickel using ABA and differential pulse-adsorptive cathodic strippingvolt...

Methidathion, a non-systemic organophosphorous insecticide and acaricide is studied at the hanging mercury drop electrode under cathodic stripping mode by means of cyclic and square-wave voltammetry (SWV). Its electrode reaction is analyzed in the light of recent theory of cathodic stripping processes of insoluble salts of SWV. Its complex electrode mechanism is described by an electrode reacti...

Trace amounts of thallium(I) can be determined using adsorptive cathodic stripping voltammetry in the presence of Xylenol Orange (XO). The reduction current of the thallium(I)-XO complex ion was measured by square-wave cathodic stripping voltammetry. The peak potential was at -0.44 V vs. Ag/AgCl. The effect of various parameters (pH, ligand concentration, accumulation potential and collection t...