We studied whether arsenic, nickel, and chromium compounds that are human carcinogens could induce transformation of cultured primary human diploid foreskin cells (HFC). All nickel compounds tested, PbCrO<, K2Cr2O7, CrO3, Na2HAsO4, NaAsO2, and jV-methyl-A/'-nitro/V-nitrosoguanidine (MNNG) caused significant (p = 0.001) dose-de pendent inductions of anchorage-independent colonies in HFC. kl l.. ...

A mild, efficient and fast method for the oxidation of alcohols and trimethylsilyl and tetrahydropyranyl ethers to their corresponding carbonyl compounds using CrO3 in the presence of sulfonic acid functionalized ordered nanoporous Na+-montmorillonite (SANM) and under solvent-free conditions is reported. All reactions were performed at room temperature in high to excellent...

A mild, efficient and fast method for the oxidation of alcohols and trimethylsilyl and tetrahydropyranyl ethers to their corresponding carbonyl compounds using CrO3 in the presence of sulfonic acid functionalized ordered nanoporous Na+-montmorillonite (SANM) and under solvent-free conditions is reported. All reactions were performed at room temperature in high to excellent...

Any substantial move of energy sources from fossil fuels to renewable resources requires large scale storage of excess energy, for example, via power to fuel processes. In this respect electrochemical reduction of CO2 may become very important, since it offers a method of sustainable CO production, which is a crucial prerequisite for synthesis of sustainable fuels. Carbon dioxide reduction in s...

A systematic catalytic investigation of the sulfur dioxide oxidation reactivity of several binary (MxOy/TiO2) and ternary (V2O5/ MxOy/TiO2) supported metal oxide catalysts was conducted. Raman spectroscopy characterization of the supported metal oxide catalysts revealed that the metal oxide components were essentially 100% dispersed as surface metal oxide species. Isolated fourfold coordinated ...

We previously showed that carcinogenic nickel, arsenic, and chromium(VI) compounds induced anchorage independence (AI) in diploid human fibroblastic cells (HFC) derived from foreskins (K. A. Biedermann and J. R. Landolph, Cancer Res., 47: 3815-3823, 1987). To elucidate the role of the valence state of chromium and solubility of chromium compounds in inducing AI, we studied the ability of solubl...