In this work, carbon nanosheet (CNS) based electrode was designed for electrochemical biosensing of glucose. CNS has been obtained by the pyrolysis of barley at 600-750 °C in a muffle furnace; it was then purified and functionalized. The CNS has been characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and Raman spectroscopic techniques. The electrochemical activity of C...

Electrochemical oxidation of resorcinol in aqueous medium using boron-doped diamond anode (BDD) was investigated in a batch electrochemical reactor in the presence of Na2SO4 supporting electrolyte. The effect of process parameters such as resorcinol concentration (100-500 g/L), current density (2-10 mA/cm2), Na2SO4 concentration (0-20 g/L), and reaction temperature (25-45°C) was analyzed on ele...

Hg(2+) ions are bound to a 1,4-benzenedimethanethiol (BDMT) monolayer assembled on a Au electrode. Electrochemical reduction of the Hg(2+)-BDMT monolayer to Hg(+)-BDMT (at E degrees =0.48 V) and subsequently to Hg(0)-BDMT (at E degrees =0.2 V) proceeds with electron-transfer rate constants of 8 and 11 s(-1), respectively. The Hg(0) atoms cluster into aggregates that exhibit dimensions of 30 nm ...

Copper nanoparticles were fabricated by electro-reduction of CuSO4solution in the presence of cetyltrimethylammonium bromide (CTAB) cationic surfactant as an additive through potentiostatic method. The prepared copper nanoparticles were characterized by scanning electron microscopy (SEM) and electrochemical methods. The SEM images reveal that the nanoparticles with diameters at about 70 n...

A high sensitive electrochemical nanostructure sensor based on graphene oxide/Fe3O4@SiO2 nanocomposite modified graphite screen printed electrode (GO/Fe3O4@SiO2/SPE) has been developed for trace analysis of acetaminophen. The electrochemical study of the modified electrode, as well as its efficiency for simultaneous voltammetric oxidation of acetaminophen and tryptophan is described. Compared w...

In this work, CuO nanoparticles (CuO NPs) was prepared by a simple and green method using Rosmarinus officinalis extract containing phenolic constituents as both the chelating and the stabilizing agents. CuO nanoparticles/polyorthoaminophenol composite (CuO NPs/POAP) as electro-active electrodes for electrocatalytic oxidation of methanol with good uniformity are prepared by electropolymerizatio...

In the present paper, the electrochemical properties of magnetic iron oxide nanoparticles (Fe2O3 and Fe3O4) as highly sensitive sensors for the simultaneous determination of hydrazine and hydroxylamine was described. The electrochemical behavior of hydrazine and hydroxylamine was investigated using cyclic voltammetry, chronoamperometry and differentia...

Thymus is regarded as one of the medicinal species, which according to obtained chromatograms of floral water of Thymus; one of the main components is thymol as strong antioxidant. In this study the appropriate and physically powerful correlation was found between the anti-radical and oxidation potentials. The antioxidant activity of the Thymus was measured by using square wave and cyclic volta...

the electrochemical preparation of poly-n-methylpyrrole (pmpy) coated platinum electrode in chloroform in the presence of tetrabutylammonium perchlorate, hexafluorophosphate, hydrogensulphate, periodate and iodide as supporting electrolytes was performed. the influence of electrosynthesis method, dopant anion type and operation temperature on electrochemical behavior of polymer were demonstrate...

The redox properties of sulfite ion has been examind using cyclic voltammetry in acetonitrile solvent at the surface of gold, pelatin and glassy carbon electrodes. It has bben found tha, sulfite ion exhibits two electron oxidation peak with EC’ mechanism. A novel chemically modified electrode containing Prussian blue complex and multi wall carbon nanotubes (MWCNs) was achieved on the surface of...