the reduction mechanism of molybdenum-methyl thymol blue (mtb)-chlorate system has been investigated in water on a mercury electrode. as this system is very sensitive for ultratrace determination of molybdenum, the actual mechanism involved was studied. electrochemical techniques, including dc tast polarography and cyclic voltammetry were employed. it is shown that, the cathodic wave of molybde...

this work is aimed to evaluate the role of nanoclay in the protective performance of an eco-friendly silane sol-gel layer applied on mild steel substrate in 0.1m sodium chloride solution. at the first step, the effect of ph of the silane solution, consisting of a mixture of γ-glycidoxypropiltrimethoxysilane and methyltriethoxysilane and tetraethoxysilane, on the coating performance was evaluate...

In food sector, there is a huge demand for rapid, reliable, user & eco-friendly biosensors to analyse the quality and safety of food products. Biosensor based methodology depends upon the recognition of a specific antigens or receptors by corresponding antibodies, aptamers or high-affinity ligands. The first scientifically commercialised sensors were the electrochemical sensors used for the ana...

In this study, yttrium aluminum garnet (YAG) was prepared using a facile electrochemical technique. Four samples were synthesized in 0, 20, 40 and 60°C by electrochemical pulse deposition and were then calcined at 1200°C. The effect of synthesis temperature on morphology and structure of YAG was studied using X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron micro...

In this paper, the effect of penicillin G drug as a green corrosion inhibitor on mild steel in 1.0 Mhydrochloric acid solution has been investigated using potentiodynamic polarization, electrochemicalimpedance spectroscopy (EIS) and electrochemical noise (EN) techniques. The inhibition efficiencywas found to increase with increasing inhibitor concentration. Potentiodynamic polarizationmeasureme...

This paper focused on the characterization of electrochemical behavior of a martensitic stainless steel in the acidic solutions. For this purpose, electrochemical parameters were derived from potentiodynamic polarization, Mott Schottky analysis and electrochemical impedance spectroscopy (EIS) techniques. The potentiodynamic polarization results showed that corrosion current density of AISI 420 ...

The anodization of titanium has been an excellent option for protecting and its alloys from corrosive environments such as acids chloride systems, by generating a homogenous oxide layer. objective the current investigation was to evaluate electrochemical corrosion behavior Ti-6Al-2Sn-4Zr-2Mo Ti-6Al-4V anodized in 1M H2SO4 H3PO4 solutions at density 2.5 × 10–3 A/cm2. anodization’s characterizati...