We report an investigation of water adsorption in the hydrophobic metal-organic framework Al(OH)(1,4-naphthalenedicarboxylate) by means of molecular simulation. We show how simple molecular models allow us to reproduce the experimental isotherm, and how grand canonical Monte Carlo simulations can help elucidate the question of the thermodynamic nature of the adsorption transition, which turns o...

Recently, a new simple method for the purification of CdSe-CdS-ZnS quantum dots by using membrane filtration, the filtration process, successfully separated the oleic acid from quantum dots through membranes purification after synthesis; purification of quantum dots is a very significant part of post synthetical treatment that determines the properties of the material. We explore the possibilit...

the recovery and removal of the most organic acids in liquid solutions is usually treated with fixed-bed adsorption processes. among many adsorbents, granular activated carbon (gac) is used to remove organic pollutants such as benzoic acid (ba) from wastewaters conventionally. in this research, adsorption isotherm curves of ba onto gac at varying temperatures 25-60 °c are developed and the amou...

The effect of molecular weight on the crystallization behavior poly(lactic acid) (PLA) both isothermally and non-isothermally was studied using differential scanning calorimetry polarized optical microscopy. Two distinct crystal forms (? ??) were investigated under normal conditions for different weights. Using microscopy, growth rate spherulites measured nucleation estimated. Heterogeneous mor...

Analytical ultracentrifugation is one of the classical techniques for the study of protein interactions and protein self-association. Recent instrumental and computational developments have significantly enhanced this methodology. In this paper, new tools for the analysis of protein self-association by sedimentation velocity are developed, their statistical properties are examined, and consider...

The thermodynamic and transport properties of diffusing species in microporous materials are strongly influenced by their interactions with the confining framework, which provide the energy landscape for the transport process. The simple topology and the cellular nature of the alpha cages of a ZK4 zeolite suggest that it is appropriate to apply to the study of the problem of diffusion in tight ...

Sorption-desorption kinetics play a major role in transport and bioavailability of pollutants in soils. Contaminant concentration is a potentially important factor controlling kinetics. A previous paper dealt with the effect of solute concentration on fractional uptake rates of phenanthrene and pyrene from a finite aqueous source. In this study we determined the effect of initial phenanthrene s...