In this work, we determined thermophysical properties such as electrical conductivity and refractive index for 1-propyl-3-methylimidazolium bromide, [PrMIm]Br in ternary mixtures of [PrMIm]Br + ethylene carbonate + water at T = (298.2, 308.2 and 318.2) K and 0.1MPa. Conductometric measurements were carried out for [PrMIm]Br ionic liquid in ethylene carbonate + water solvent mixture in various c...

Klockmannite copper selenide nanosheets (CuSe NSs) are synthesized by a facile microwave-assisted method and fully characterized. The nanosheets have smooth surface and hexagonal shape. The lateral size is 200-500 nm × 400-800 nm and the thickness is 55 ± 20 nm. The current-voltage characteristics of CuSe NS films show unique Ohmic and high-conducting behaviors, comparable to the thermally-depo...

Pit-and-fissure caries lesions contribute greatly to the caries incidence in permanent molar teeth in children. To date, the diagnosis of occlusal caries is still performed mainly by visual inspection, periodically aided by bite-wing radiography. However, in detecting small occlusal carious lesions, these methods perform inadequately, especially in low caries prevalence populations or individua...

The development of the multivalent electrolytes is a critical component to advance polyvalent energy storage technology. In this work, new and simple nonaqueous zinc electrolyte developed investigated where secondary amine introduced as cosolvent. addition dimethylamine (DMA) cosolvent in THF facilitates solubilization Zinc (II) bis(trifluoromethanesulfonyl)imde (Zn(TFSI) 2 ) results homogeneou...

Ti/PbO2/Sb2O3 electrode was used as indicator electrode in potentiometric and conductometric titration in aqueous solution at 298 K. The E-pH curve is linear with a slope of 0.0505 V/dec at 298 K which is close to the theoretical value 2.303RT/F (0.059 V at 298 K). The standard potential of this electrode, E, is computed with respect to the SCE as reference electrode. The recovery percentages f...

A new series of unsymmetrical macrocyclic complexes of tin(ll) has been prepared by the template process using bis(3-oxo-2-butylidene)propane-1,3-diamine as precursor. This affords a method to synthesize these complexes with various ring sizes. The tetradentate macrocyclic precursor [N(4)mL] reacts with SnCl(2) and different diamines in a 1:1:1 molar ratio in refluxing methanol to give complexe...

New binuclear Co(II) and Co(II) complexes of ONO tridentate heterocyclic Schiff base derived from 4-aminoantipyrine with salicylaldehyde have been synthesized and characterized on the bases of elemental analysis, UV-Vis., FT-IR, and also by aid of molar conductivity measurements, magnetic measurements, and melting points. It has been found that the Schiff bases with Cu(II) or Co(II) ion forming...

In this work, we investigate the controlled fabrication of Sn-doped TiO2 nanorods (Sn/TiO2 NRs) for photoelectrochemical water splitting. Sn is incorporated into the rutile TiO2 nanorods with Sn/Ti molar ratios ranging from 0% to 3% by a simple solvothermal synthesis method. The obtained Sn/TiO2 NRs are single crystalline with a rutile structure. The concentration of Sn in the final nanorods ca...

Tetraazamacrocyclie complexes of lead and palladium have been synthesized by the template process using the bis(benzil)ethylenediamine precursor. The tetradentate macrocycle (maL) reacts with PbCl(2), PdCl(2) and different diamines in a 1:1:1 molar ratio in methanol to give several solid complexes of the types [Pb(maL)(R)Cl(2)] and [Pd(maL)(R)]Cl(2) (where R = 2,6-diaminopyridine or 1,2-phenyle...