The oxidation of aniline to azobenzene was conducted in the presence of either monolayer graphene (EG) or graphene-oxide-like surface, such as GOx, under ultra-high vacuum conditions maintaining a 365-nm UV light exposure to enhance the oxidation reaction. The surface-bound products were investigated using micro Raman spectroscopy, high-resolution photoemission spectroscopy, and work function m...

In this work, modification of carbon paste electrode surface with poly (2, 5-Dimethyl aniline) (P-2,5-DMA) by using electrochemical polymerization was described. Then, transition metal ions of Ni(II) were incorporated into the polymer film by two ways. At first way, the polymeric modified electrode was immersed in 0.2 M NiSO4 solutions and the second way was carried out by electrodeposition of ...

Increasing numbers of workers in industry are working a novel or unusual 12-hr workshift in which the exposure time is longer and the recovery period is shorter than for a standard 8-hr workshift. Experiments were conducted to examine the effects of altering the exposure schedule of rats from 8 hr/day for 5 days to 12 hr/day for 4 days on the toxicity resulting from the inhalation of aniline at...

The synthesis and properties of new monoazo dyes derived from the diazonium salts of paminobenzoic acid, 3-trifluoromethyl aniline , 4-trifluoromethyl aniline are considered .Theprepared compounds were characterized by UV-Visible , FT-IR and H NMR spectroscopictechniques . The effect of varying solvent upon the absorption ability of p-amino benzoic acidcoupled with 4,4 —diethyl aniline , anilin...

Waterborne polyaniline (PANI) dispersion has got extensive attention due to its environmental friendliness and good processability, whereas the storage stability and mechanical property have been the challenge for the waterborne PANI composites. Here we prepare for waterborne PANI dispersion through the chemical graft polymerisation of PANI into epichlorohydrin modified poly (vinyl alcohol) (EP...

Low-toxicity magnetic nanocarriers (MNCs) composed of a shell of poly [aniline-co-N-(1-one-butyric acid) aniline] over a Fe(3)O(4) magnetic nanoparticle core were developed to carry recombinant tissue plasminogen activator (rtPA) in MNC-rtPA for targeted thrombolysis. With an average diameter of 14.8 nm, the MNCs exerted superparamagnetic properties. Up to 276 μg of active rtPA was immobilized ...