the fe-mcm-22 zeolite was found to be an efficient solid heterogeneous catalyst for synthesis of dihydropyrano [2,3-c] pyrazoles via one pot four component reaction of ethyl acetoacetate, hydrazine hydrate, aromatic aldehyde and malononitrile in aqueous alcohol. the catalyst was synthesized by hydrothermal method under autogenous pressure and modified by fe (iii) ion exchange. the prepared cata...

The realization of large powerful all-solid-state batteries is still hampered by the availability of environmentally friendly and low-cost Li ion conductors that can easily be produced on a large scale and with high reproducibility. Advanced solid electrolytes benefit from fast ion-selective transport and non-flammability, but they may have low electrochemical stability with respect to Li metal...

Urban landfill leachate is a high strength wastewater characterized by high concentrations of recalcitrant organic compounds, ammonia and, increasingly, arsenic. The aims of this study were the review on membrane bioreactor, ion exchange and adsorption method for landfill leachate treatment. Membrane bioreactor (MBR) can be used for wastewater and landfill leachate treatment. The most important...

Solid-liquid extraction (adsorption or ion exchange) is a promising approach for the in situ separation of organic acids from fermentation broths. In this study, a diluted concentration of lactic acid (<10 g/L) separation from a model fermentation broth by granular activated carbon (GAC) as well as weak (Reillex® 425 or RLX425) and strong (Amberlite® IRA-400 or AMB400) base anion exchange resin...

We report on Auger stimulated ion desorption via Coulomb explosion from surface self-assembled alkylthiol and fluorocarbon molecular layers, triggered by K-capture decay of an imbedded radioactive 55Fe atom. The charge state of the ejecta is determined by charge exchange in binary atomic collisions in bulk and electron tunneling outside the solid, as well as by fragmentation of electronically e...

Highly porous polypyrrole (PPy)-nanocellulose paper sheets have been evaluated as inexpensive and disposable electrochemically controlled three-dimensional solid phase extraction materials. The composites, which had a total anion exchange capacity of about 1.1 mol kg(-1), were used for extraction and subsequent release of negatively charged fluorophore tagged DNA oligomers via galvanostatic oxi...

Antibody-free approaches for quantitative LC-MS/MS-based protein bioanalysis are reviewed and critically evaluated, and compared with the more widely used immunoaffinity-based approaches. Antibody-free workflows will be divided into four groups and discussed in the following order: direct analysis of signature peptides after proteolytic digestion; enrichment of target proteins and signature pep...

The dicationic clusters [(CsMes)41r4S4]2+ ( [112+) and [(C5Me5)31r3S~]2+ ([2]*+) were prepared by treatment of [ (C5Me~)IrCl2]2 with (Me3Si)zS followed by ion exchange chromatography. Crystallographic characterization of the tetrairidium cluster [ 112+ reveals a cubane motif consisting of interpenetrated Ir4 and S4 tetrahedra. The Ir4 core is distorted from idealized tetrahedral symmetry by vir...

a r t i c l e i n f o The oxygen exchange and diffusion properties of La 0.6 Sr 0.4 CoO 3 − δ thin films on yttria stabilized zirconia were analyzed by impedance spectroscopy and 18 O tracer experiments. The investigations were performed on the same thin film samples and at the same temperature (400 °C) in order to get complementary information by the two methods. Electrochemical impedance spec...