نتایج جستجو برای: thermodynamic equation of state
تعداد نتایج: 21236870 فیلتر نتایج به سال:
this work is presented in five parts. in the first part preparation of the starting complex [pt(c^n)cl(dmso)], 1, in which c^n = n(1),c(2?)-chelated, deprotonated 2-phenylpyridine, and dmso = dimethylsulfoxide, and its reaction with 1 equiv of the biphosphine ligands bis(diphenylphosphino)amine, dppa, or bis(diphenylphosphino)methane, dppm, to give the complex [pt(c^n)cl(dppa)], 2, or [pt(c^n)c...
In high-pressure dynamic thermodynamic processes, the pressure is much higher than the air critical pressure, and the temperature can deviate significantly from the Boyle temperature. In such situations, the thermo-physical properties and pneumatic performance can’t be described accurately by the ideal gas law. This paper proposes an approach to evaluate the pneumatic performance of a high-pres...
supercritical carbon dioxide has gained increasing attention in food and pharmaceutical processing owing to the fact that it is environmentally inexpensive, not flammable, essentially non-toxic, and it has a convenient critical point. also, it has been attracting much attention in many fields, such as extraction of sensitive materials and pharmaceutical processing and polymerization processes. ...
Abstract In the causal theory of relativistic dissipative fluid dynamics, there are conditions on the equation of state and other thermodynamic properties such as the second-order coefficients of a fluid that need to be satisfied to guarantee that the fluid perturbations propagate causally and obey hyperbolic equations. The second-order coefficients in the causal theory, which are the relaxatio...
Recently, the author suggested a simple and composite equation of state by incorporating fundamental thermodynamic properties like heat capacities into her earlier concise equation of state for gases based on free volume and molecular association / dissociation. This work brings new results for aqueous solutions, based on the analogy of the equation of state for gases and solutions over wide ra...
This note is a supplement to our previous papers: Mod. Phys. Lett. A14 (1999) 2427 (math-ph/9911010); Int. J. Mod. Phys. A15 (2000) 2329 (math-ph/9912014). The thermodynamic Bethe ansatz (TBA) equation for an integrable spin chain related to the Lie superalgebra osp(1|2) is analyzed. The central charge determined by low temperature asymptotics of the specific heat can be expressed by the Rogers...
finding a representative fluid in a hydrocarbon reservoir is crucial for integrated reservoir management. in this study, a systematic approach for screening and selecting consistent fluid samples in a reservoir was developed. the model integrated quality control (qc) of well conditioning before sampling, qc of pvt data, thermodynamic modeling and compositional gradient within a reservoir. well ...
The present work is the successful extension of an improved equation of state (EOS) to refrigerant fluids. The objective is the prediction of isothermal and saturated liquid densities of refrigerants. Two temperature-independent parameters appearing in the modified EOS are closely related to critical point properties of refrigerant fluids. Our results showed that, the proposed EOS can predict w...
The mathematical structure imposed by the thermodynamic critical point motivates an approximant that synthesizes two theoretically sound equations of state: the parametric and the virial. The former is constructed to describe the critical region, incorporating all scaling laws; the latter is an expansion about zero density, developed from molecular considerations. The approximant is shown to yi...
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