calculate some thermodynamic properties of molten polymers including specific volume and isothermal compressibility (s.m. hoseini, physical chemistry & electrochemistry, 2 (2014) 56-65). this work extended that eos to predict the volumetric properties of some molten ethylene copolymers including ethylene/1-octene, ethylene/1-butene (xethylene equal to 0.8543 and 0.563), ethylene/propene. the ab...

an analytical equation of state (eos) developed by ihm-song-mason (ism) has been applied tocalculate some thermophysical properties of molten polymers including poly (1-octene) (po), poly (vinylmethyl ether) (pvme), poly (vinyl chloride) (pvc), and poly (styrene) (ps). three temperature-dependentparameters of the ism eos have been determined based on the alternative scaling constants, dispersiv...

an analytical equation of state was applied to calculate the thermodynamic properties for argon.the equation of state is that of song and mason. it is based on a statistical-mechanical perturbationtheory of the hard convex bodies and can be written as fifth-order polynomial in the density. thereexist three temperature-dependent parameters: the second virial coefficient, an effective molecularvo...

using the lennard-jones (12-6) potential, a new equation of state is obtained that can predict properties of both gases and liquids relatively well. this equation of state is given as (z-a)v2=(a/v2)-b, where z is the compressibility factor, a and b are constants, and a is an adjustable parameter that depends on the temperature, volume and the nature of the fluid, and its expressions depends upo...

an analytical equation of state by song and mason is developed to calculate the pvt properties ofmercury. the equation of state is based on the statistical-mechanical perturbation theory of hard convexbodies and can be written as a fifth-order polynomial in the density. there exists three temperaturedependentparameters in the equation of state; the second virial coefficient, an effective molecu...

This paper presents the ability of a new group contribution equation of state in the prediction of thermodynamic properties of alcohols, ketones and ethers. This equation of state, called MCORGC, is based on the Chain-Of-Rotators Group Contribution equation considering a NRTL type local composition mixing rule. The group parameters required to predict the thermodynamic properties of the oxygena...

An analytical equation of state was applied to calculate the thermodynamic properties for argon.The equation of state is that of Song and Mason. It is based on a statistical-mechanical perturbationtheory of the hard convex bodies and can be written as fifth-order polynomial in the density. Thereexist three temperature-dependent parameters: the second virial coefficient, an effective molecularvo...