YBa2Cu3O7 d (YBCO or Y123) films on rolling-assisted biaxially textured substrates (RABiTS) were prepared via a fluorinefree metallorganic deposition (MOD) through spin coating, burnout, and high temperature anneal. The effects of substrate texture and surface energy of the CeO2 cap layer were investigated. Except for the commonly accepted key factors, such as the textures of substrate and buff...

Nano-crystalline particles of CeO2 have been synthesized by a low temperature chemical precipitation method. The precursor materials used in this research were Ce(NO3)3.6H2O, NaOH and diethylene glycol as surfactant. X-ray powder diffraction results showed that face centered cubic CeO2 nanoparticles with crystalline size in nanometer scale were formed. Scanning electron microscopy measurement s...

pure anatase titania (tio2), mixed 1.0 wt.% cerium-anatase titania (1.0 wt.%ceo2-tio2), and mixed 1.0 wt.% zirconia-anatase titania (1.0 wt.%zro2-tio2) nano powders were synthesized by co-precipitation method and characterized using x-ray diffraction (xrd), brunauer-emmett-teller (bet) surface area analysis, uv-vis diffuse reflectance spectroscopy (drs), and transmission electron microscope (te...

Cerium dioxide (CeO2) nanoparticles have found wide use in industrial and commercial products, such as coating materials, fuel additives, and nanomedicine, to name a few. As such, it is expected that CeO2 nanoparticles (NPs) will find their way into the environment and may be transported via aqueous systems where they may end up in drinking water and/or plants, both of which increase the possib...

Nowadays engineered nanomaterials (ENM) are widely present in different areas of our life. Large application of ENM in daily used customer products leads to its released into the environment. The fate of ENM in aquatic system isn’t clearly understood that pose the threat for leaving organisms and for human health. Before making the risk assessment and the toxicity tests ENM should be fully char...

DFT+U calculations of the structure of CeO2(111)-supported Aubased bimetallic nanoclusters (NCs) show that a strong support−metal interaction induces a preferential segregation of the more reactive element to the NC−CeO2 perimeter, generating an interface with the Au component. We studied several Au -based bimetallic NCs (Au-X, X: Ag, Cu, Pd, Pt, Rh, and Ru) and found that (Au− Cu)/CeO2 is opti...

We studied the interactions between the carboxylate anchoring group from trimethylacetic acid (TMAA) and CeO2(111) surfaces as a function of oxygen stoichiometry using in situ X-ray photoelectron spectroscopy (XPS). The stoichiometric CeO2(111) surface was obtained by annealing the thin film under 2.0 × 10(-5) Torr of oxygen at ∼550 °C for 30 min. In order to reduce the CeO2(111) surface, the t...

CeO2, ZrO2, and a series of CexZr1-xO2 catalysts with 1 wt% Pd were exposed to fixed exposures of SO2 under oxidizing environments and then characterized by FTIR, pulse-reactor studies with CO and O2, and temperature-programmed desorption (TPD). For exposures above 473 K, sulfates were formed on all of the materials; however, the results are consistent with the formation of bulk sulfates on CeO...

We demonstrate that the compressibility of cubic fluorite-structure CeO2 nanocrystals s10 nmd increases at pressures above ,20 GPa. At ambient pressure, CeO2 nanocrystals exhibit larger cell parameters than micro-sized samples, and initially exhibit a higher bulk modulus of 328s12d GPa. However, above 20 GPa, the bulk modulus is reduced to 230s10d GPa. Thus, a critical pressure of ,20 GPa was d...