Proton transfer (PT) and methyl group transfer (MGT) occurring in small biomimetic systems, Formamide-Formamidic acid (FA-FI), and N-formyl-N-methylformamide-(E)-methyl N-formylformimidate (NMFA-NMFI) are investigated in the gas phase and in single-walled carbon nanotubes by using the density functional theory and the ONIOM approach. It is shown that PT reaction is disfavoured in single-walled ...

In this paper, a novel design of all-solid photonic bandgap fiber with ultra-low confinement loss is proposed. The confinement loss is reduced remarkably by managing the number of rods rings, up-doping level, pitch value, and rods diameters. Moreover, the designed PCF shows ultra-flattened dispersion in L- and U-band. Furthermore, a new design, based on introducing of an extra ring of air h...

physical modeling for study of deep foundations can be performed in simple chambers (1g), calibration chambers (cc), and centrifuge apparatus (ng). these common apparatus face certain limitations and difficulties. recently, frustum confining vessels (fcv) have been evolved for physical modeling of deep foundations and penetrometers. shaped as the frustum of a cone, this device applies steady pr...

The fluctuation-induced dynamo effect, resulting from the correlation between electron pressure fluctuation and radial magnetic in core, is measured by an cyclotron radiometer Faraday-effect polarimetry high-temperature tokamak plasmas. acts to flatten parallel current core of a confinement fusion device.

We present an absolute measurement of the total ion-drag force on one single microparticle at the edge of the dust free region in low pressure complex plasmas: the void. In order to do so, the particle confinement position was monitored as a function of the gas pressure for two particle sizes under normal gravity conditions and under microgravity conditions during parabolic flights. At the bord...

The stagnation pressure p(s) of imploding cylindrical ( n = 2) and spherical ( n = 3) shells is found to scale as p(s)/p(0)~M(2(n+1)/(gamma+1))(0), where M0 is the Mach number of the imploding shell and p(0) its maximum pressure. The result holds approximately for Mach numbers in the range 2<M0<25 relevant for inertial confinement fusion capsules and is of key importance for their ignition ener...

Quantitative measurements were carried out on the pressure effect of superheating of Al nanoparticles encapsulated in Al2O3 shells without epitaxial interfaces. In situ XRD experiments revealed that encapsulated Al nanoparticles with different particle sizes can be superheated to 7–15 K beyond the bulk equilibrium melting point of Al, and that this is accompanied by a suppressed thermal expansi...

High-speed photography was used to study the collapse of a confined two-dimensional, air cavity in water, subjected to a propagating pressure disturbance. The 5–6 mm diameter cavity was confined in a rectangular duct. A sustained pressure disturbance was created by an accelerating piston in contact with the water 240 mm away from the bubble. The pressure increased from 0.1 MPa to about 0.12 MPa...