Electron-impact detachment cross sections for H− are calculated using time-dependent close-coupling theory. The three-electron wavefunction is expanded in terms of a product of a frozen core 1s hydrogenic wavefunction and a correlated two-electron wavefunction which fully describes the ejected and scattered electrons at all times following the collision. Ejected-energy differential and total in...

Twenty-six cat retinae were surgically detached by injecting fluid into the subretinal space (SRS). The retinae were then studied by light and electron microscopy at detachment intervals ranging from 1/2 hr to 14 months. Degenerative and proliferative changes occur at the retinal pigment epithelial (RPE)-photoreceptor interface very soon after detachment, and the severity of these changes depen...

Detachment experiments have been carried out in the linear plasma device Magnum-PSI by increasing gas pressure near target. In order to a proper detailed analysis of mechanism behind momentum and power loss detachment, quantitative match is pursued between B2.5-Eunomia solutions experimental data. B2.5 multi fluid code Eunomia Monte Carlo solver for neutral particles, they are coupled together ...

Characteristic mass differences between fragment ions from backbone cleavage of RNA by electron detachment (d, w) and fragment ions from collisionally activated dissociation (c, y) provide extensive sequence information. Structure analysis by this approach should be especially useful for the detailed characterization of synthetic or post-transcriptionally modified RNA.

We report measurements of the negative ion photoelectron spectra of the simple aluminum hydride anions: AlH2(-), AlH3(-), Al2H6(-), Al3H9(-), and Al4H12(-). From these spectra, we measured the vertical detachment energies of the anions, and we estimated the electron affinities of their neutral counterparts. Our results for AlH2(-), AlH3(-), and Al2H6(-) were also compared with previous predicti...

The structural analysis of sulfated carbohydrates such as glycosaminoglycans (GAGs) has been a long- standing challenge for the field of mass spectrometry. The dissociation of sulfated carbohydrates by collisionally- activated dissociation (CAD) or infrared multiphoton dissociation (IRMPD), which activate ions via vibrational excitation, typically result in few cleavages and abundant SO(3) loss...

Electron attachment and detachment kinetics of 2-C(4)F(8) were studied over the temperature range 298-487 K with a flowing-afterglow Langmuir-probe apparatus. Only parent anions were formed in the attachment process throughout this temperature range. At the highest temperatures, thermal electron detachment of the parent anions is important. Analysis of the 2-C(4)F(8) gas showed an 82/18 mixture...