نتایج جستجو برای: electron detachment

تعداد نتایج: 321826  

1999
F. Robicheaux

A method is presented for accurately calculating the total electron impact detachment cross section for weakly bound negative ions. The results are compared to recent experiments for electron impact detachment of H and B. Cross sections differential in energy are presented which elucidate some of the dynamics of the detachment process. A scaling law for the cross section is proposed. [S0031-900...

Journal: :Journal of the American Society for Mass Spectrometry 2012
Franklin E Leach Mellisa Ly Tatiana N Laremore Jeremy J Wolff Jacob Perlow Robert J Linhardt I Jonathan Amster

Electron detachment dissociation (EDD) has previously provided stereo-specific product ions that allow for the assignment of the acidic C-5stereochemistry in heparan sulfate glycosaminoglycans (GAGs), but application of the same methodology to an epimer pair in the chondroitin sulfate glycoform class does not provide the same result. A series of experiments have been conducted in which glycosam...

Journal: :Journal of the American Society for Mass Spectrometry 2007

Journal: :Physical review letters 2003
M V Frolov N L Manakov E A Pronin Anthony F Starace

We present a model-independent theory for laser detachment of a weakly bound electron having a nonzero angular momentum. Our treatment reduces to the well-known Keldysh result for tunnel ionization upon neglecting rescattering effects. Numerical results for the above-threshold detachment spectrum of a negative ion having an outer p electron show significant modification of the rescattering plat...

2008
Jonathan Tennyson

Calculations are presented which use the molecular R-matrix with pseudostates (MRMPS) method to treat electron impact electron detachment and electronic excitation of the carbon dimer anion. Resonances are found above the ionisation threshold of C−2 with 1Σ+g , Πg and Πg symmetry. These are shape resonances trapped by the effect of an attractive polarisation potential competing with a repulsive...

Journal: :Journal of the American Society for Mass Spectrometry 2008

Journal: :Physical chemistry chemical physics : PCCP 2016
Michael A Parkes Ciara Phillips Michael J Porter Helen H Fielding

Understanding how the interactions between a chromophore and its surrounding protein control the function of a photoactive protein remains a challenge. Here, we present the results of photoelectron spectroscopy measurements and quantum chemistry calculations aimed at investigating how substitution at the coumaryl tail of the photoactive yellow protein chromophore controls competing relaxation p...

Journal: :International Journal of Mass Spectrometry 2009

1997
MACIEJ GUTOWSKI PIOTR SKURSKI KENNETH D. JORDAN

Ž . Dipole-bound anionic states of CH CN, C H , and HF were studied using highly 3 3 2 2 correlated electronic structure methods and extended one-electron basis sets. The electron detachment energies were calculated using the coupled cluster method with single, double, and noniterative triple excitations. Geometrical relaxation of the molecular framework upon electron attachment and the differe...

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