A stopped-flow injection liquid-liquid extraction (SF-EX-FIA) spectrophotometric method is reported for the determination of palladium(II), using the 2,2'-dipyridyl-2-pyridylhydrazone (DPPH) as a color forming reagent. The colored complex Pd(II)-DPPH was extracted in CHCl(3) and the absorbance was monitored at 560 nm. An injection valve was used as a commutator in order to combine the stopped-f...

The present work deals with a numerical investigation on an experimental single cylinder direct injection Diesel engine. Calculations are carried out Kiva3v2 code using multidimensional detailed chemistry. study was predicted CO, and NOx emission levels by the engine before exhaust valve opening. Correlations proposed for NO, function of fuel, O2, N2 concentrations maximum in-cylinder pressure ...

Original scientific paper In principle, an exhaust system influences the maximum output and characteristic of a two-stroke combustion engine. The first part of the contribution deals with the possibility of transformation in a maximum output and a range of exploitable speed values by means of the change of exhaust manifold length in exhaust pipe section. This knowledge covers an output curve va...

The combustion in future engines will work with a very high amount of recirculated exhaust gas in part load conditions to enable a low peak combustion temperature. This combustion suffers from instabilities of the process and a highly nonlinear behaviour. The paper presents the use of neural nets for observing the engine. A nonlinear model without feedback of measurements is linearised online a...

Exposure to vehicle exhaust can drive up to 70 % of excess lifetime cancer incidences due to air pollution in urban environments. Little is known about how exhaust-derived particles and organic pollutants, implicated in adverse health effects, are affected by freezing ambient temperatures and the presence of snow. Airborne particles and (semi)volatile organic constituents in dilute exhaust were...

With the growing number of new exhaust after-treatment systems, fuels and fuel additives for internal combustion engines, efficient and reliable methods for detecting exhaust genotoxicity and mutagenicity are needed to avoid the widespread application of technologies with undesirable effects toward public health. In a commonly used approach, organic extracts of particulates rather than complete...