The threshold-ion-pair-production (TIPP) spectra of H2S and D2S have been recorded in the vicinity H++SH?[X1?+(v?=0,1;J?)] D++SD?[X1?+(v?=0,1;J?)] thresholds using a tunable vacuum-ultraviolet laser cold molecular samples (Trot?20K) supersonic expansions. ion-pair-production signal was found to be much stronger at v?=0 than v?=1 thresholds. From rotational structure spectra, dominant photodisso...

INTRODUCTION Mobile-phase ion chromatography (MPIC) is a technique that combines ion-pair chromatography with suppressed conductivity detection. Ion-pair chromatography is commonly used in combination with UV detection, in which case it is referred to as reversedphase ion-pair chromatography (RPIPC). MPIC has the advantage of using conductivity detection, which serves as a universal detection m...

A concept of the ion pair with the interionic distance (r0) of 2–3 nm in carrier generation process of photoconductive polymer films has been believed for a long time. Recently, however, the experimental and theoretical results denying the distant ion pair born from thermalization have been reported. This brief review describes our paper addressing the controversy over the ion pair in photocond...

Results of an experimental study on the unusual "inverse" charge state (H(+)Na(-)) in salts where the H(+) ion is sequestered, combined with our earlier theoretical calculations on an unsequestered model compound (Me(3)N-H(+)...Na(-)), prompted us to further investigate such systems. In particular, we examined Et(3)N-H(+)...K(-) because considerations of the proton affinity of the amine and of ...

The second-generation poly(ethylene imine) dendrimer (L), based on ammonia as the initiating core molecule, forms anion and ion-pair complexes in aqueous solution. Speciation of the complex species formed and determination of the relevant stability constants were performed by means of potentiometric titration in a 0.10 M NMe4Cl solution at 298.1 K. Protonated forms of L interact with NO3(-), SO...

The excited-state proton transfer and subsequent intramolecular ion pair formation of a cupreidine-derived Cinchona organocatalyst (BnCPD) were studied in THF-water mixtures using picosecond time-resolved fluorescence together with global analysis. Full spectral and kinetic characterization of all the fluorescent species allowed us to monitor the 3-step process for the ion pair dissociation. In...

the computer simulation program of a practical scale reverse electrodialysis process has been developed based on the program for saline water electrodialysis. the program is applied to compute the performance of an industrial-scale reverse electrodialysis stack (effective membrane area s = 1 m × 1 m = 1 m2, cell pair number n = 300 pairs). the stack operatingconditions are optimized. seawater a...

The present work reported density, viscosity, speed of sound, electrical conductivity and refractive index data of L-alanine in the aqueous solutions of 1-hexyl-3-methylimidazolium ibuprofenate at T= 298.15 K. Using the measured data, partial molar volume of transfer ( ), partial molar isentropic compressibility of transfer ( ), viscosity B-coefficient of transfer (∆traB), ion association const...

Abstract The formation of dust ion-acoustic shocks (DIASs) in a four-component quantum plasma whose constituents are electrons, both positive and negative ions and immobile charged dust grains, is studied. The effects of both the dissipation due to kinematic viscosity and the dispersion caused by the charge separation as well as the quantum tunneling due to the Bohm potential are taken into acc...