The low-affinity interaction between human serum albumin (HSA) and Diclofenac sodium (DCF) was studied using NMR techniques. Both 13C-NMR chemical shift and linewidth show that the dichlorophenyl ring in DCF molecule plays a primary role in its interaction with HSA. Langmuir adsorption isotherm was applied to evaluate the association constant K and the number of binding sites n of the drug/HSA ...

Bernal suggested that clays might have played a significant role in primitive earth through the process of concentration and adsorption of the biologically formed biomonomers and thus protecting them against hydrolytic fission.Adsorption of adenine was studied in presence of montmorillonite clay with or without cations Ca+,Cu+,Mg+.Studies carried out have shown that adsorption of adenine was de...

Microwave stabilized heavy metal sludge was used as an adsorbent to remove the copper ions from aqueous solution. The adsorption characteristics of copper on the stabilized-sludge were studied by various models, such as Freundlich and Langmuir isotherm equation. Results show that the pH(zpc) of stabilized-sludge was at 9.2-9.5. Moreover, the adsorption of copper ions onto the stabilized-sludge ...

In this paper, the Langmuir-Freundlich isotherm is used to model the interaction of several triazines (desethylatrazine, desisopropylatrazine, simazine, atrazine, propazine and prometryn) with a propazine-imprinted polymer and to explain the observed cross-reactivity. Different rebinding experiments (each herbicide alone or all together in a mixture) were carried out and the experimental bindin...

Complexing agents are extensively applied in many fields of industry. They are used to provide effective controlling trace metal ions in cleaning industries, textile, pulp and paper production, water treatment, agriculture, food industries, etc. Recently, the low biodegradability of these ligands and their accumulation in the environment has become a cause for concern. Therefore, replacement of...

This study investigated the feasibility of Date-palm) Phoenix dactylifera (Leaf Ash (DLA) (an inexpensive agricultural-byproduct) as an application to adsorb Pb(II) ions. An adsorption process was carried out to evaluate initial concentration Pb(II) ions, adsorbent dose, contact time, pH and temperature on the systematic removal of Pb(II). The effects were examined and results showed that remov...

Polyaniline titanotungstate (PATiW) was synthesized by the sol-gel method. Adsorption isotherm studies of Cs from aqueous solution are described. Elemental Composition, chemical solubility, ion-exchange capacity (IEC) and pH titration are studied. Distribution coefficients (Kd) for ten metal ions have been determined. It was found that the polyaniline titanotungstate has high affinity and high ...

almcm-41 was applied for adsorption of methylene blue (mb) and auramine (au) in single and binary component systems. in the single component systems, almcm-41 represents higher adsorption capacity for mb than au with the maximal adsorption capacity of 2.07×10−4 and 1.15×10−4 mol/g at 25 ˚c for mb and au, respectively. in the binary component system, mb and au exhibit competitive adsorption onto...

The potential of water hyacinth ash for phenol adsorption from aqueous solution was studied. Batch kinetic and isotherm studies were carried out under varying experimental conditions of contact time, phenol concentration, adsorbent dosage and pH. The adsorption of phenol decreased with increasing pH. The Freundlich and Langmuir adsorption models were used for the mathematical description of ads...