Electron spin resonance (ESR) spin trapping was utilized to investigate the generation of free radicals from oxidation of sodium sulfite, nickel(II) sulfite, and nickel subsulfide (Ni3S2) by ambient oxygen or H2O2 at pH 7.4. The spin trap used was 5,5-dimethyl-1-pyrroline-N-oxide (DMPO). Under ambient oxygen, a solution of sodium sulfite alone generated predominantly sulfur trioxide anion radic...

In this work, various 3-cyano-4-aryl-4H-pyran derivatives were prepared efficiently through a one-pot,multicomponent synthesis between aromatic aldehyde, malononitrile and acetophenone derivativesor ethyl acetoacetate using Fe3O4/EDTA magnetic nanocatalyst and ethanol as solvent. The reactionswere completed at room temperature in 10 min using 5 mg of catalyst and 2 mL of solvent to prepare1 mmo...

The burden of life on the earth is the source of biological contamination in water. Nanotechnology has promising contributions in control of microbial contaminations and medicinal plants further increase these properties. Presently, copper acetate and nickel oxide nanoparticles were synthesized using 1mM solution of each with Ziziphus mauritiana leaves extract as reducing agent. Nanoparticles w...

abstract: background: release of volatile organic compounds (vocs) in industrial and urban area have adverse effects on human health and  environment. the aim of this study was removal of gaseous toluene, as the most of pollutants among vocs, by using of tio 2 nanoparticles coated on nickel foam substrate. methods: tio 2 nanoparticles prepared by sol gel method and coated on nickel foam. morpho...

Approximately 10% of the population in the USA suffer from nickel allergy, and many are unable to wear jewellery or handle coins and other objects that contain nickel. Many agents have been developed to reduce the penetration of nickel through skin, but few formulations are safe and effective. Here, we show that applying a thin layer of glycerine emollient containing nanoparticles of either cal...

Liprin-α4 was strongly induced following nickel (II) chloride exposure in a variety of cell types including BEAS-2B, A549, BEP2D and BL41 cells. Liprin-α4, a member of the Liprin alpha family, has seven isoforms but only three of these variants were detected in BEAS-2B cells (004, 201 and 202). The level of Liprin-α4 variants 201 and 004 were highly increased in BEAS-2B cells in response to nic...

background & aims of the study: heavy metals are the most important and main pollutants because of their accumulation and high toxicity even at very low dose and cause serious hazards to ecological system as well as human health. thus, their removal has been challenged from drinking water and industrial waters with different technologies. the purpose of this work is to investigate the removal o...

Catalytically graphitized electrospun carbon nanofibers adorned uniformly with fine nickel nanoparticles were successfully prepared. The procedure was based on the electrospinning technique and the use of nickel precursor to create both graphitized nanofibers and nickel nanoparticles under a relatively low-temperature heat treatment. The X-ray diffraction and Raman results clearly proved cataly...

In this research nickel zinc ferrite nanoparticles with composition of Ni1-xZnxFe2O4 (where x=0, 0.3, 0.7, 1) were synthesized by a sol-gel method at 600 °C for 5 hours. The structure of nanoparticles was studied using X-ray diffraction pattern. The lattice parameter of ferrite nanoparticles was calculated and indicates lattice constant of nanoparticl...